Structural, Spectroscopic, and Computational Analysis of Heterometallic Thorium Phosphinidiide Complexes.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c02308
Abstract: To synthesize complexes with thorium-phosphorus multiple-bond character, reactions of (C5Me5)2Th[P(H)Mes]2 with monovalent alkali-metal bases, MN(SiMe3)2, as well as CuMes, have been investigated. The results with MN(SiMe3)2 are phosphinidiide complexes of the form {(C5Me5)2Th[μ2-P(Mes)][μ2-P(H)Mes]M(L)n}2 (M =… read more here.
Keywords: c5me5 2th; phosphinidiide complexes; thorium; structural spectroscopic ... See more keywords
Multinuclear Cu(I) Clusters Featuring a New Triply Bridging Coordination Mode of Phosphaamidinate Ligands.
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DOI: 10.1021/acs.inorgchem.8b01422
Abstract: Phosphabenzamidine [mes-NH-C(Ph)═P-mes) (1) and phosphaformamidine (mes-NH-CH═P-mes) (4) ligands have been synthesized and characterized. The conjugate bases of 1 and 4 coordinate by each bridging three Cu(I) ions, forming hexa- and tetranuclear clusters Cu6[mes-N═C(Ph)-P-mes]3Cl4Li(THF)2 (3) and… read more here.
Keywords: coordination mode; multinuclear clusters; clusters featuring; mes mes ... See more keywords
High diversity of Morchella and a novel lineage of the Esculenta clade from the north Qinling Mountains revealed by GCPSR-based study
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DOI: 10.1038/s41598-019-56321-1
Abstract: China is a mainland country rich in natural morel recourses, having records of half of the worldwide 61 morel phylospecies. In this study, 31 collections of ascocarps from the north Qinling Mountains, 4 collections of… read more here.
Keywords: lineage; morchella; mel; qinling mountains ... See more keywords