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Reactions of Silanone(silyl)tungsten and -molybdenum Complexes with MesCNO, (Me2SiO)3, MeOH, and H2O: Experimental and Theoretical Studies

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Published in 2017 at "Organometallics"

DOI: 10.1021/acs.organomet.6b00958

Abstract: Reactions of silanone(silyl)tungsten and -molybdenum complexes Cp*(OC)2M{O═SiMes2(DMAP)}(SiMe3) (M = W (1a), Mo (1b), Cp* = η5-C5Me5, Mes = 2,4,6-Me3C6H2, DMAP = 4-(Me2N)C5H4N) with MesCNO, (Me2SiO)3, MeOH, and H2O were investigated. No silanone trapping product was… read more here.

Keywords: tungsten molybdenum; product; reactions silanone; molybdenum complexes ... See more keywords