A Springloaded Metal-Ligand Mesocate Allows Access to Trapped Intermediates of Self-Assembly.
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DOI: 10.1021/acs.inorgchem.8b00370
Abstract: A strained, "springloaded" Fe2L3 iminopyridine mesocate shows highly variable reactivity upon postassembly reaction with competitive diamines. The strained assembly is reactive toward transimination in minutes at ambient temperature and allows observation of kinetically trapped intermediates… read more here.
Keywords: self assembly; mesocate allows; intermediates self; metal ligand ... See more keywords