Mannose‐Inspired Mesoionic Carbenes: Building Antitumor Palladium(II) Allyl Complexes
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DOI: 10.1002/ejic.202500382
Abstract: The synthesis and anticancer evaluation of palladium(II) complexes bearing mannose‐conjugated mesoionic carbenes and their triazolium precursors (triazolium palladates) is reported. Ligand precursors are easily obtained via copper‐catalyzed azide–alkyne cycloaddition. Palladium allyl carbene complexes are prepared… read more here.
Keywords: palladium; inspired mesoionic; mesoionic carbenes; carbenes building ... See more keywords
Half-Sandwich Ir(III) and Os(II) Complexes of Pyridyl-Mesoionic Carbenes as Potential Anticancer Agents
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DOI: 10.1021/acs.organomet.9b00327
Abstract: A series of cationic chlorido arene-iridium(III) and arene-osmium(II) complexes with bidentate pyridyl functionalized mesoionic carbenes (MIC) of the 1,2,3-triazol-5-ylidene type have been prepared... read more here.
Keywords: sandwich iii; iii; iii complexes; half sandwich ... See more keywords
Redox-Paired Reductive Heck Reaction and Oxidative Esterification Catalyzed by Mesoionic Carbenes.
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DOI: 10.1021/acs.orglett.4c02762
Abstract: Paring a reductive reaction and an oxidative reaction in one reaction could be immensely important in achieving atom economic and environmental advantages. Herein, we report a simple protocol that combines two such reductive Heck reactions… read more here.
Keywords: reaction; oxidative esterification; mesoionic carbenes; reaction oxidative ... See more keywords