A mesoionic nitrogen-donor ligand: structure, iridium coordination, and catalytic effects.
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DOI: 10.1039/c7dt04555g
Abstract: A mesoinic pyridylideneamide ligand (PYA) was synthetized and fully characterized and coordinated to an iridium(iii) center. This ligand represents the first example of a mesoionic N-donor ligand. Structural and spectroscopic analysis revealed unique properties which… read more here.
Keywords: donor ligand; mesoionic nitrogen; nitrogen donor; iridium ... See more keywords