A Polymer‐Oriented Self‐Assembly Strategy toward Mesoporous Metal Oxides with Ultrahigh Surface Areas
Sign Up to like & getrecommendations! Published in 2019 at "Advanced Science"
DOI: 10.1002/advs.201801543
Abstract: Abstract Mesoporous metal oxides (MMOs) have attracted comprehensive attention in many fields, including energy storage, catalysis, and separation. Current synthesis of MMOs mainly involve use of surfactants as templates to generate mesopores and organic reagents… read more here.
Keywords: polymer oriented; mesoporous metal; metal; metal oxides ... See more keywords
A General Polymer-Oriented Acid-Mediated Self-Assembly Approach toward Crystalline Mesoporous Metal Sulfides.
Sign Up to like & getrecommendations! Published in 2021 at "Small"
DOI: 10.1002/smll.202100428
Abstract: Mesoporous metal sulfides (MMSs) with high surface areas and large pore volumes show great potential in many applications such as gas sensing, photodetection, and catalysis. However, the synthesis of MMSs is still challenging due to… read more here.
Keywords: polymer oriented; mesoporous metal; metal sulfides; metal ... See more keywords
Heterogeneous catalysts based on mesoporous metal–organic frameworks
Sign Up to like & getrecommendations! Published in 2017 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2017.10.014
Abstract: Abstract Mesoporous metal–organic frameworks (meso-MOFs) are emerging as promising functional materials for heterogeneous catalysis due to their high surface area, porosity, readily adjustable structures and tunable functionalities. Their properties and functions are often dictated by… read more here.
Keywords: mesoporous metal; heterogeneous catalysts; metal organic; meso mofs ... See more keywords
Hierarchical mesoporous metal–organic frameworks encapsulated enzymes: Progress and perspective
Sign Up to like & getrecommendations! Published in 2021 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2021.214032
Abstract: Abstract Hierarchical mesoporous metal–organic frameworks (HM-MOFs) with adjustable mesopores have shown great potential for the encapsulation of enzyme because of their enhanced performance for enzymatic catalysis. The evolution of HM-MOFs encapsulated enzymes has resulted in… read more here.
Keywords: organic frameworks; mesoporous metal; encapsulated enzymes; hierarchical mesoporous ... See more keywords
Polymer-oriented evaporation induced self-assembly strategy to synthesize highly crystalline mesoporous metal oxides
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2020.125527
Abstract: Abstract Mesoporous metal oxides (MMOs) with high crystallinity and large surface area, as compared with its counterparts, show better performance in many applications. Current synthesis of MMOs mainly uses amphiphilic block copolymers as templates to… read more here.
Keywords: polymer oriented; mesoporous metal; oriented evaporation; metal ... See more keywords
Soft-to-hard consecutive templating one-pot route from metal nitrate/phenol resin/surfactant to mesoporous metal oxides with enhanced thermal stability
Sign Up to like & getrecommendations! Published in 2020 at "Microporous and Mesoporous Materials"
DOI: 10.1016/j.micromeso.2019.109767
Abstract: Abstract Mesoporous materials with crystalline ZrO2, Y2O3, and CeO2 frameworks were one-pot synthesized from a clear solution of ethanol containing metal nitrates, organic surfactant (i.e., Pluronic® F-127), formaldehyde, and phloroglucinol. The solution was converted to… read more here.
Keywords: mesoporous metal; metal; nitrate phenol; metal nitrate ... See more keywords
Preparation and application of peptide molecularly imprinted material based on mesoporous metal-organic framework.
Sign Up to like & getrecommendations! Published in 2021 at "Talanta"
DOI: 10.1016/j.talanta.2020.121765
Abstract: In this study, a new molecularly imprinted material, MIP@UiO-66-NH2, was synthesized with glutathione (GSH) as template and mesoporous metal organic framework (UiO-66-NH2) as matrix. The molecularly imprinted polymer was modified on the surface and into… read more here.
Keywords: uio nh2; mesoporous metal; imprinted material; metal organic ... See more keywords
Stable Molecular Surface Modification of Nanostructured, Mesoporous Metal Oxide Photoanodes by Silane and Click Chemistry.
Sign Up to like & getrecommendations! Published in 2019 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.8b17824
Abstract: Binding functional molecules to nanostructured mesoporous metal oxide surfaces provides a way to derivatize metal oxide semiconductors for applications in dye-sensitized photoelectrosynthesis cells (DSPECs). The commonly used anchoring groups, phosphonates and carboxylates, are unstable as… read more here.
Keywords: nanostructured mesoporous; mesoporous metal; surface; chemistry ... See more keywords
Surface-Seal Encapsulation of a Homogeneous Catalyst in a Mesoporous Metal-Organic Framework.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c11573
Abstract: A rapid surface sealing strategy has been developed for the encapsulation of a homogeneous catalyst, phosphotungstic acid (PTA), in a mesoporous metal-organic framework (MOF), MIL-101(Cr). This new surface polymerization method utilizes non-solvent-induced phase separation to… read more here.
Keywords: catalyst; surface; mesoporous metal; metal organic ... See more keywords
Assessing negative thermal expansion in mesoporous metal–organic frameworks by molecular simulation
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Chemistry A"
DOI: 10.1039/c9ta06644f
Abstract: Molecular simulations reveal that mesoporous metal–organic frameworks display large volumetric negative thermal expansion, which has a considerable effect on mechanical stability, outlining an alternative application for these ultra-porous materials. read more here.
Keywords: thermal expansion; negative thermal; mesoporous metal; metal organic ... See more keywords
A mesoporous metal–organic framework used to sustainably release copper(ii) into reducing aqueous media to promote the CuAAC click reaction
Sign Up to like & getrecommendations! Published in 2022 at "RSC Advances"
DOI: 10.1039/d2ra04298c
Abstract: The mesoporous metal–organic framework Cr-MIL-101-NH2 (MOF1) has been used to encapsulate, by a simple impregnation method, large amounts of copper sulfate. The resulting loaded material, Cu@MOF1, was successfully employed to slowly release copper(ii) into an… read more here.
Keywords: copper; reaction; organic framework; release copper ... See more keywords