Rh(III)-Catalyzed meta-C-H Alkenylation with Alkynes.
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DOI: 10.1021/jacs.8b11038
Abstract: Rh(III)-catalyzed meta-C-H functionalization reactions are still rare. Herein, we report the first example of Rh(III)-catalyzed meta-C-H alkenylation with disubstituted alkynes directed by a U-shaped nitrile template. Exclusive regio-selectivity has been achieved using unsymmetrical aryl and… read more here.
Keywords: alkenylation alkynes; catalyzed meta; meta alkenylation; iii catalyzed ... See more keywords