Ruthenium-Catalyzed ortho- and meta-H/D Exchange of Arenes.
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DOI: 10.1021/acs.orglett.9b03955
Abstract: Ruthenium-catalyzed aromatic H/D exchange in [D4]acetic acid has been developed. By using N-heteroarenes as directing groups, both ortho and meta positions are selectively deuterated with high levels of D incorporation. Moreover, this strategy provides an… read more here.
Keywords: catalyzed ortho; exchange arenes; meta exchange; ortho meta ... See more keywords