Monomeric Octahedral Ruthenium(II) Complex Enabled meta-C-H Nitration of Arenes with Removable Auxiliaries.
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DOI: 10.1021/acs.orglett.7b01297
Abstract: A removable oxime-assisted meta-C-H nitration of arenes is reported. Mechanistic investigations and DFT calculations reveal a new monomeric octahedral ruthenium(II) complex is responsible for the meta-selective nitration. Dioxygen as a cooxidant is crucial for achieving… read more here.
Keywords: meta nitration; nitration; octahedral ruthenium; ruthenium complex ... See more keywords