Influence of alkali metal amides on the catalytic activity of manganese nitride for ammonia decomposition
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DOI: 10.1016/j.cattod.2016.09.010
Abstract: Abstract Strong promoting effect of alkali metal amides, i.e., LiNH2, NaNH2 and KNH2, on the catalytic activity of manganese nitride (MnN) for ammonia decomposition has been demonstrated, which is evidenced by ca. 100 K drop in… read more here.
Keywords: alkali metal; metal amides; metal; catalytic activity ... See more keywords
Intermolecular addition of alcohols to carbodiimides catalyzed by rare-earth metal amides
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DOI: 10.1039/c7qo00991g
Abstract: A novel catalytic behavior of simple rare-earth metal amides RE[N(SiMe3)2]3 (RE = La(1), Nd(2), Sm(3), Yb(4), Y(5)) in the intermolecular addition of alcohols to carbodiimides was disclosed. A series of isoureas were obtained in good… read more here.
Keywords: addition; earth metal; intermolecular addition; rare earth ... See more keywords
Tailoring Carbene–Metal–Amides for Thermally Activated Delayed Fluorescence: A Computationally Guided Study on the Effect of Cyclic (Alkyl)(amino)carbenes
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DOI: 10.3390/molecules28114398
Abstract: Gold-centered carbene–metal–amides (CMAs) containing cyclic (alkyl)(amino)carbenes (CAACs) are promising emitters for thermally activated delayed fluorescence (TADF). Aiming at the design and optimization of new TADF emitters, we report a density functional theory study of over… read more here.
Keywords: alkyl amino; carbene metal; thermally activated; cyclic alkyl ... See more keywords