Metal Atom-Doped Co3 O4 Hierarchical Nanoplates for Electrocatalytic Oxygen Evolution.
Sign Up to like & getrecommendations! Published in 2020 at "Advanced materials"
DOI: 10.1002/adma.202002235
Abstract: Electrocatalysts based on hierarchically structured and heteroatom-doped non-noble metal oxide materials are of great importance for efficient and low-cost electrochemical water splitting systems. Herein, the synthesis of a series of hierarchical hollow nanoplates (NPs) composed… read more here.
Keywords: oxygen evolution; metal atom; metal; co3 hierarchical ... See more keywords
Role of the Metal Atom in a Carbon-Based Single-Atom Electrocatalyst for LiS Redox Reactions.
Sign Up to like & getrecommendations! Published in 2022 at "Small"
DOI: 10.1002/smll.202200395
Abstract: Carbon-based single metal atom catalysts (SACs) are being extensively investigated to improve the kinetics of the Li-S redox reaction, which is greatly important for batteries with cell-level energy densities >500 W h kg-1 . However, there are contradictory reports… read more here.
Keywords: carbon based; geometry; based single; metal atom ... See more keywords
Hyperfine interactions and metal atom dynamics in a number of t-butyl ferrocene derivatives: The counter intuitive effects of ring substitution
Sign Up to like & getrecommendations! Published in 2019 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.118972
Abstract: Abstract Using temperature-dependent Mossbauer effect spectroscopy, the hyperfine interactions and metal atom dynamics of three structurally related 1,1′ bis tert. butyl ferrocenes have been examined in detail over the temperature range 90 tert. butyl groups… read more here.
Keywords: metal atom; atom dynamics; interactions metal; ring substitution ... See more keywords
DFT-based study of single transition metal atom doped g-C3N4 as alternative oxygen reduction reaction catalysts
Sign Up to like & getrecommendations! Published in 2019 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2019.04.057
Abstract: Abstract In this paper, the stability and the oxygen reduction reaction (ORR) catalytic activity of single transition metal atom doped g-C3N4 catalysts, M-C3N4 (M = Mn, Fe, Co, Ni, Cu, Rh, Pd, Ag, Pt, Au), were investigated… read more here.
Keywords: metal atom; transition metal; oxygen reduction; metal ... See more keywords
Metal–Metal Bond Umpolung in Heterometallic Extended Metal Atom Chains
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c02118
Abstract: Understanding the fundamental properties governing metal–metal interactions is crucial to understanding the electronic structure and thereby applications of multimetallic systems in catalysis, material science, and magnetism. One such property that is relatively underexplored within multimetallic… read more here.
Keywords: metal bond; metal atom; metal; metal metal ... See more keywords
Symmetry Breaking in a Triferrous Extended Metal Atom Chain
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.4c02752
Abstract: Semilocal and random phase approximation (RPA) density functional theory (DFT) and complete active space (CASSCF + NEVPT2) methodologies were applied to investigate a new class of extended metal atom chain (EMAC) complexes. A novel triferrous… read more here.
Keywords: atom chain; metal atom; extended metal; symmetry breaking ... See more keywords
The structure of a pentachromium(II) extended metal atom chain at 3 K: Cotton's conjecture proven.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt03103e
Abstract: We provide definitive experimental proof that the archetypal string-like compound [Cr5(tpda)4(NCS)2] has alternating long and short Cr-Cr separations in the solid state, as conjectured by F. A. Cotton, rather than essentially equally spaced Cr atoms,… read more here.
Keywords: structure pentachromium; pentachromium extended; atom chain; cotton ... See more keywords
Tunnel barrier to spin filter: Electronic-transport characteristics of transition metal atom encapsulated in a small Cadmium Telluride cage.
Sign Up to like & getrecommendations! Published in 2022 at "Nanoscale"
DOI: 10.1039/d2nr06134a
Abstract: First-principles theory-based comparative electronic-transport studies were performed for an atomic chain of Au, a bare Cd9Te9 cage-like cluster, and a single transition metal (TM) (Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ru, Rh,… read more here.
Keywords: cage; tunnel barrier; atom encapsulated; transition metal ... See more keywords
Metal atom chemistry as a direct pathway to access homoleptic mono- and dinuclear isonitrile compounds of the iron triad Fe, Co, and Ni.
Sign Up to like & getrecommendations! Published in 2025 at "Dalton transactions"
DOI: 10.1039/d5dt01275a
Abstract: The co-condensation of atomic metal vapors of iron, nickel and cobalt with toluene, followed by a direct reaction with isonitriles, between -30 °C and -78 °C, yields stable homoleptic metal isonitrile complexes. Complexes of Fe,… read more here.
Keywords: chemistry; chemistry direct; metal atom; atom chemistry ... See more keywords
A review on functional nanoarchitectonics nanocomposites based on octahedral metal atom clusters (Nb6, Mo6, Ta6, W6, Re6): inorganic 0D and 2D powders and films
Sign Up to like & getrecommendations! Published in 2022 at "Science and Technology of Advanced Materials"
DOI: 10.1080/14686996.2022.2119101
Abstract: ABSTRACT This review is dedicated to various functional nanoarchitectonic nanocomposites based on molecular octahedral metal atom clusters (Nb6, Mo6, Ta6, W6, Re6). Powder and film nanocomposites with two-dimensional, one-dimensional and zero-dimensional morphologies are presented, as… read more here.
Keywords: metal atom; atom clusters; nanocomposites based; octahedral metal ... See more keywords
Foreword to the focus issue: metal atom clusters and superatoms: from fundamentals to functional nanocomposites
Sign Up to like & getrecommendations! Published in 2024 at "Science and Technology of Advanced Materials"
DOI: 10.1080/14686996.2024.2377923
Abstract: The nanometre-sized metal atom clusters (nanoclusters) or superatoms ( read more here.
Keywords: atom clusters; clusters superatoms; metal atom; focus issue ... See more keywords