Insights into the Metal-CO Bond in O2M(η1-CO) (M = Cr, Mo, W, Nd, and U) Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03257
Abstract: Investigations on the structures and bonding properties of metal carbonyl compounds provide fundamental understandings on the origin of small-molecule activations. Herein, the geometry and bonding trends of a series of isovalent metal oxocarbonyl complexes O2M(η1-CO)… read more here.
Keywords: metal bond; o2m complexes; geometry; insights metal ... See more keywords
Metal–Metal Bond Umpolung in Heterometallic Extended Metal Atom Chains
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DOI: 10.1021/acs.inorgchem.2c02118
Abstract: Understanding the fundamental properties governing metal–metal interactions is crucial to understanding the electronic structure and thereby applications of multimetallic systems in catalysis, material science, and magnetism. One such property that is relatively underexplored within multimetallic… read more here.
Keywords: metal bond; metal atom; metal; metal metal ... See more keywords
Metal–Metal Bond in the Light of Pauling’s Rules
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DOI: 10.3390/molecules26020304
Abstract: About 70 years ago, in the framework of his theory of chemical bonding, Pauling proposed an empirical correlation between the bond valences (or effective bond orders (BOs)) and the bond lengths. Till now, this simple… read more here.
Keywords: bond light; bond; chemistry; metal bond ... See more keywords