Revisiting ultra-weak metal-metal bonding
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Physics Letters"
DOI: 10.1016/j.cplett.2019.06.023
Abstract: Abstract Quantum mechanical calculations have been carried out to reinvestigate the possibility of formation of true triple bond between s-block metals (Be, Mg, Ca) supported by different s1 type donors (Li, Na, Cu). The existence… read more here.
Keywords: metal metal; revisiting ultra; metal; metal bonding ... See more keywords
Cluster-Geometry-Associated Metal-Metal Bonding in Trimetallic Carbide Clusterfullerenes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01399
Abstract: Geometry configurations of the metallic clusters play a significant role in the involved bonding nature. Herein, we report the crystallographic characterization of unprecedented erbium-based trimetallic clusterfullerenes, namely, Er3C2@Ih(7)-C80, in which the inner Er3C2 cluster presents… read more here.
Keywords: geometry associated; metal bonding; geometry; metal ... See more keywords
Metal-Metal Bonding in Actinide Dimers: U2 and U2.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c06417
Abstract: Understanding direct metal-metal bonding between actinide atoms has been an elusive goal in chemistry for years. We report for the first time the anion photoelectron spectrum of U2-. The threshold of the lowest electron binding… read more here.
Keywords: metal bonding; bonding actinide; metal; metal metal ... See more keywords
Metal-Metal Bonding as an Electrode Design Principle in the Low-Strain Cluster Compound LiScMo3O8.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c12070
Abstract: Electrode materials for Li+-ion batteries require optimization along several disparate axes related to cost, performance, and sustainability. One of the important performance axes is the ability to retain structural integrity though cycles of charge/discharge. Metal-metal… read more here.
Keywords: electrode; compound; metal bonding; design ... See more keywords
Contrasting the group 6 metal-metal bonding in sodium dichromate(ii) and sodium dimolybdate(ii) polymethyl complexes: synthetic, X-ray crystallographic and theoretical studies.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c6dt04644d
Abstract: Extending the class of group 6 metal-metal bonded methylate compounds supported by alkali metal counter-ions, the first sodium octamethylmolybdate(ii) complex [(TMEDA)Na]4Mo2Me8 and heptamethylchromate(ii) relations [(donor)Na]3Cr2Me7 (donor is TMEDA or TMCDA) are reported. The former was… read more here.
Keywords: metal bonding; group metal; sodium; metal ... See more keywords
High Quality Pt–Pt Metal Bonding for High Temperature Packaging
Sign Up to like & getrecommendations! Published in 2022 at "Micromachines"
DOI: 10.3390/mi13091543
Abstract: Platinum is an ideal material for high-temperature resistant device packaging due to its higher melting point and good electrical properties. In this paper, the thermocompression bonding of Pt–Pt metal electrodes was successfully realized through process… read more here.
Keywords: quality; metal bonding; temperature; packaging ... See more keywords