Correlating cluster size and NLO response of complexes aggregated with bifurcated metal bonds: a DFT study
Sign Up to like & getrecommendations! Published in 2017 at "Structural Chemistry"
DOI: 10.1007/s11224-017-1009-9
Abstract: In the present work, the cooperativity effect on the NLO response of clusters aggregated with bifurcated metal bonds is reported by DFT calculations at the CAM-B3LYP/6-311++G(d,p) level. Linear clusters of (LiN(CHO)2)1-5 and (NaN(CHO)2)1-5 which are… read more here.
Keywords: metal bonds; nlo response; bifurcated metal; cluster size ... See more keywords
Making Heterometallic Metal-Metal Bonds in Keggin-Type Polyoxometalates by a Six-Electron Reduction Process.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03769
Abstract: Polyoxometalates (POMs) represent a promising class of molecular electron reservoirs. However, their multielectron reduction gives rise to intricate physical-chemical phenomena that must be fully understood for their future use in energy-storage devices. Herein, we show… read more here.
Keywords: keggin type; metal bonds; six electron; metal ... See more keywords
Substrate-Modulated Synthesis of Metal-Organic Hybrids by Tunable Multiple Aryl-Metal Bonds.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c01338
Abstract: Assembly of semiconducting organic molecules with multiple aryl-metal covalent bonds into stable one- and two-dimensional (1D and 2D) metal-organic frameworks represents a promising route to the integration of single-molecule electronics in terms of structural robustness… read more here.
Keywords: aryl metal; multiple aryl; metal organic; metal bonds ... See more keywords