Morphology-Engineering Construction of Anti-Aggregated Co/N-Doped Hollow Carbon from Metal-Organic Frameworks for Efficient Biomass Upgrading.
Sign Up to like & getrecommendations! Published in 2023 at "Small"
DOI: 10.1002/smll.202207689
Abstract: The controlled pyrolysis of metal/carbon-containing precursors is commonly used for fabricating multifunctional metal/carbon-based catalysts, nevertheless, the inevitable agglomeration of these precursors in pyrolysis is extremely negative for efficient catalysis. This study reports the first example… read more here.
Keywords: carbon; metal carbon; doped hollow; morphology ... See more keywords
Persulfate activation by ZIF-67-derived cobalt/nitrogen-doped carbon composites: Kinetics and mechanisms dependent on persulfate precursor
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2020.127305
Abstract: Abstract Whereas previous studies that explored the application of metal–carbon composites as persulfate activators have focused on synergistic performance improvements, the potential advantages or features that can be acquired by integrating metal and carbon constituents… read more here.
Keywords: doped carbon; carbon; metal carbon; persulfate ... See more keywords
Metal–carbon bond strengths under polymerization conditions: 2,1-insertion as a catalyst stress test
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2017.04.013
Abstract: Abstract Quantitative agreement between experimentally determined M–C bond dissociation energies (BDE) and DFT predictions (M06-2X/TZ//TPSSTPSS/DZ) can be reached by choosing the correct anchor for experimentally derived BDE. For the example of the archetypical metallocene catalyst… read more here.
Keywords: polymerization conditions; carbon; metal carbon; bond ... See more keywords
Wetting Behavior and Mechanism between Hot Metal and Carbon Brick
Sign Up to like & getrecommendations! Published in 2021 at "Journal of The European Ceramic Society"
DOI: 10.1016/j.jeurceramsoc.2021.04.062
Abstract: Abstract Wetting behavior between hot metal and carbon brick is the first step to explore the erosion of carbon brick. In order to investigate the wetting behavior, wetting experiments between hot metal (with carbon content… read more here.
Keywords: carbon brick; hot metal; metal carbon; wetting behavior ... See more keywords
Predicted Adsorption Affinity for Enteric Microbial Metabolites to Metal and Carbon Nanomaterials
Sign Up to like & getrecommendations! Published in 2022 at "Journal of Chemical Information and Modeling"
DOI: 10.1021/acs.jcim.2c00492
Abstract: Ingested nanomaterials are exposed to many metabolites that are produced, modified, or regulated by members of the enteric microbiota. The adsorption of these metabolites potentially affects the identity, fate, and biodistribution of nanomaterials passing the… read more here.
Keywords: adsorption; microbial metabolites; metal carbon; affinity ... See more keywords
Biocompatible Collagen/Liquid Metal/Carbon Nanotube Hydrogel for Electromagnetic Interference Shielding in Bioelectronics.
Sign Up to like & getrecommendations! Published in 2025 at "ACS sensors"
DOI: 10.1021/acssensors.5c02645
Abstract: The rapid advancement of implantable bioelectronics and wireless medical devices has made electromagnetic interference (EMI) shielding a critical challenge, particularly for ensuring signal stability in cardiac pacemakers, neural implants, and biosensors. However, achieving stable EMI… read more here.
Keywords: metal carbon; collagen; liquid metal; electromagnetic interference ... See more keywords
Stereoelectronic Modulation of a Single-Molecule Junction through a Tunable Metal-Carbon dπ-pπ Hyperconjugation.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c02733
Abstract: Conjugated molecules play a critical role in the construction of single-molecule devices. However, most conventional conjugated molecules, such as hydrocarbons, involve only a pπ-pπ conjugation of light elements. While the metal d-orbitals can introduce abundant… read more here.
Keywords: metal carbon; single molecule; metal; carbon hyperconjugation ... See more keywords
Metal–carbon bonding in early lanthanide substituted cyclopentadienyl complexes probed by pulsed EPR spectroscopy
Sign Up to like & getrecommendations! Published in 2024 at "Chemical Science"
DOI: 10.1039/d3sc06175b
Abstract: We examine lanthanide (Ln)–ligand bonding in a family of early Ln3+ complexes [Ln(Cptt)3] (1-Ln, Ln = La, Ce, Nd, Sm; Cptt = C5H3tBu2-1,3) by pulsed electron paramagnetic resonance (EPR) methods, and provide the first characterization… read more here.
Keywords: spectroscopy; lanthanide; metal carbon; carbon bonding ... See more keywords
Soluble alkali-metal carbon nanotube salts for n-type thermoelectric composites with improved stability
Sign Up to like & getrecommendations! Published in 2021 at "Applied Physics Letters"
DOI: 10.1063/5.0047338
Abstract: We present a method to dissolve carbon nanotubes that simultaneously allows to prepare n-doped films. These films are composed of thinner bundles of longer tubes when compared to films prepared using surfactants and sonication. Their… read more here.
Keywords: carbon; alkali metal; metal carbon; carbon nanotube ... See more keywords
X-ray photoelectron spectroscopy study of the mechanism of surface functionalization of metal/carbon nanostructures with sp-elements
Sign Up to like & getrecommendations! Published in 2017 at "Physics of the Solid State"
DOI: 10.1134/s1063783417010279
Abstract: The chemical bond of the atoms on the surface of metal/carbon nanostructures functionalized with atoms of sp-elements, such as silicon, phosphorus, sulfur, nitrogen, fluorine, and iodine, and the effect of functionalization on the change in… read more here.
Keywords: carbon; metal carbon; carbon nanostructures; spectroscopy ... See more keywords
Assessing the Toxicity of Metal- and Carbon-Based Nanomaterials In Vitro: Impact on Respiratory, Intestinal, Skin, and Immune Cell Lines
Sign Up to like & getrecommendations! Published in 2024 at "International Journal of Molecular Sciences"
DOI: 10.3390/ijms252010910
Abstract: The field of nanotechnology has experienced exponential growth, with the unique properties of nanomaterials (NMs) being employed to enhance a wide range of products across diverse industrial sectors. This study examines the toxicity of metal-… read more here.
Keywords: metal carbon; cell lines; cell; carbon based ... See more keywords