Theoretical analysis of frontier orbitals, electronic transitions, and global reactivity descriptors of M(CO)4L2 type metal carbonyl complexes: a DFT/TDDFT study
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DOI: 10.1007/s11224-018-1231-0
Abstract: Metal carbonyl complexes, which have been known as effective catalysts since early days, find use in many fields both directly and indirectly. Although the use of metal carbonyl complexes as bio-probe and protein labeling agent… read more here.
Keywords: metal carbonyl; carbonyl complexes; reactivity; theoretical analysis ... See more keywords
Group 6 metal carbonyl complexes of cyclo-(P5Ph5)
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DOI: 10.1515/pac-2018-0905
Abstract: Abstract Group 6 metal (Cr, Mo, W) carbonyl complexes react with cyclo-(P5Ph5) to afford the phosphorus-rich complexes [Cr(CO)5{cyclo-(P5Ph5)-κP1}] (1), [{Cr(CO)5}2{μ-cyclo-(P5Ph5)-κP1,P3}] (2), [M(CO)4{cyclo-(P5Ph5)-κP1,P3}] (with M=Cr (3), Mo (4), W (exo-5, endo-5)) depending on the reaction conditions.… read more here.
Keywords: exo endo; complexes cyclo; group metal; carbonyl complexes ... See more keywords