Enantioselective Synthesis of Spiro Heterocyclic Compounds Using a Combination of Organocatalysis and Transition-Metal Catalysis.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical record"
DOI: 10.1002/tcr.202200284
Abstract: Over the last ten years, the combination of organocatalysis with transition metal (TM) catalysis has become one of the most important toolboxes used for synthesizing optically pure compounds containing chiral quaternary centers, including spiro heterocyclic… read more here.
Keywords: catalysis; metal catalysis; transition metal; combination organocatalysis ... See more keywords
Sustainable metal catalysis in CH activation
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DOI: 10.1016/j.ccr.2017.04.012
Abstract: Abstract The omnipresence of C H bonds in organic compounds renders them highly attractive targets for the installation of functional groups towards the construction of valuable molecular scaffolds. Consequently, C H activation has extended beyond… read more here.
Keywords: sustainable metal; catalysis activation; activation; metal catalysis ... See more keywords
Harnessing Radical Chemistry via Electrochemical Transition Metal Catalysis
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DOI: 10.1016/j.isci.2020.101796
Abstract: Summary The merger of transition metal catalysis and electroorganic synthesis has recently emerged as a versatile platform for the development of highly enabling radical reactions in a sustainable fashion. Electrochemistry provides access to highly reactive… read more here.
Keywords: chemistry; transition metal; metal catalysis;
Chiral-at-Iron Catalyst: Expanding the Chemical Space for Asymmetric Earth-Abundant Metal Catalysis.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b01352
Abstract: A new class of chiral iron catalysts is introduced that contains exclusively achiral ligands with the overall chirality being the result of a stereogenic iron center. Specifically, iron(II) is cis-coordinated to two N-(2-pyridyl)-substituted N-heterocyclic carbene… read more here.
Keywords: iron; pynhc ligands; chiral iron; metal catalysis ... See more keywords
Isonitriles as supporting and non-innocent ligands in metal catalysis.
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DOI: 10.1039/d0cs00223b
Abstract: Isonitriles, being competent σ-donors, show a strong aptitude to form transition-state metal complexes. Nevertheless, until the end of the last century, few metal-isonitrile catalyzed processes were known. Only more recently, scientists recognized the considerable potential… read more here.
Keywords: isonitriles supporting; metal catalysis; catalysis; ligands metal ... See more keywords
Recent advances in the synthesis of chiral α-tertiary amines via transition-metal catalysis.
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DOI: 10.1039/d3cc00439b
Abstract: The significance of chiral α-tertiary amines in medicinal chemistry and drug development has been unquestionably established in the last few decades. α-Tertiary amines are attractive structural motifs for natural products, bioactive molecules and pharmaceuticals and… read more here.
Keywords: metal catalysis; chemistry; tertiary amines; transition metal ... See more keywords
Recent Progress in Radical Decarboxylative Functionalizations Enabled by Transition-Metal (Ni, Cu, Fe, Co or Cr) Catalysis
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DOI: 10.1055/s-0040-1707273
Abstract: Aliphatic carboxylic acids are abundant in natural and synthetic sources and are widely used as connection points in many chemical transformations. Radical decarboxylative functionalization promoted by transition-metal catalysis has achieved great success, enabling carboxylic acids… read more here.
Keywords: transition metal; metal catalysis; radical decarboxylative; catalyzed decarboxylative ... See more keywords