Recent Developments in Transition Metal‐Catalyzed Cross‐Dehydrogenative Coupling Reactions of Ethers and Thioethers
Sign Up to like & getrecommendations! Published in 2018 at "ChemCatChem"
DOI: 10.1002/cctc.201800582
Abstract: Cross‐dehydrogenative coupling of two C−H bonds or a C−H and an X−H bond (X=N, O, P, S, etc.) has emerged as a powerful new synthetic methodology in the last 12 years. Using this approach, simple ethers,… read more here.
Keywords: transition metal; cross dehydrogenative; developments transition; metal catalyzed ... See more keywords
Transition metal catalyzed C-H functionalization through electrocatalysis.
Sign Up to like & getrecommendations! Published in 2023 at "ChemSusChem"
DOI: 10.1002/cssc.202202201
Abstract: Electrochemically promoted transition-metals catalyzed C-H functionalization has emerged as promising area of research over the last decades. However, development of this field is still at an early stage compared to the traditional functionalization reactions using… read more here.
Keywords: functionalization; catalyzed functionalization; metal catalyzed; electrochemically promoted ... See more keywords
A Computational Mechanistic Study of Metal‐Catalyzed Remote C–H Functionalizations – Insights into the Origin of Regioselectivity and the Role of Acid
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.201601111
Abstract: The metal-catalyzed remote C–H functionalization of quinoline N-oxide was investigated systematically through density functional theory calculations. We found that the coordination of the N-oxide moiety to a metal center greatly lowered the barrier to C–H… read more here.
Keywords: quinoline oxide; catalyzed remote; metal; role ... See more keywords
Transition Metal-Catalyzed Dicarbofunctionalization of Unactivated Olefins.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical record"
DOI: 10.1002/tcr.201700098
Abstract: Transition metal (TM)-catalyzed difunctionalization of unactivated olefins with two carbon-based entities is a powerful method to construct complex molecular architectures rapidly from simple and readily available feedstock chemicals. While dicarbofunctionalization of unactivated olefins has a… read more here.
Keywords: transition metal; unactivated olefins; dicarbofunctionalization unactivated; metal catalyzed ... See more keywords
Transition-Metal-Catalyzed Addition/Cyclization Reactions of the C-N Multiple Bonds Containing Species.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical record"
DOI: 10.1002/tcr.202100008
Abstract: This article describes our research work for the past decade, which involves the transition-metal-catalyzed cyclization reactions of the C-N multiple bonds containing species and their synthetic applications to access various heterocyclic compounds. The concepts of… read more here.
Keywords: addition; transition; transition metal; cyclization ... See more keywords
Transition Metal-Catalyzed Cross-Couplings of Benzylic Sulfone Derivatives.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical record"
DOI: 10.1002/tcr.202100210
Abstract: In recent years, the use of organosulfones as a new class of cross-coupling partner in transition-metal catalyzed reactions has undergone significant advancement. In this personal account, our recent investigations into desulfonylative cross-coupling reactions of benzylic… read more here.
Keywords: transition metal; sulfone derivatives; cross; metal catalyzed ... See more keywords
Metal-catalyzed synthetic strategies toward coumarin derivatives
Sign Up to like & getrecommendations! Published in 2018 at "Chemistry of Heterocyclic Compounds"
DOI: 10.1007/s10593-018-2262-6
Abstract: Modern approaches toward coumarin ring construction based on metal-catalyzed reactions significantly complement and extend the applicability of classical methods by increasing the reaction rates and product yields. The present review summarizes various approaches to the… read more here.
Keywords: catalyzed synthetic; toward coumarin; metal catalyzed; coumarin derivatives ... See more keywords
Complex Nature of Protein Carbonylation Specificity After Metal-Catalyzed Oxidation
Sign Up to like & getrecommendations! Published in 2017 at "Pharmaceutical Research"
DOI: 10.1007/s11095-017-2103-9
Abstract: ABSTRACTPurposeProtein carbonylation is an irreversible modification of Lys, Arg, Thr and Pro amino acids under conditions of oxidative stress. Previous studies have reported specific carbonylated residues in purified recombinant albumins, albeit with a lack of… read more here.
Keywords: carbonylation; site; protein carbonylation; metal catalyzed ... See more keywords
A review on transition-metal mediated synthesis of quinolines
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Chemical Sciences"
DOI: 10.1007/s12039-018-1466-8
Abstract: Quinoline is one of the important class of heterocyclic compounds which have gained considerable importance because of its high pharmaceutical efficacy and broad range of biological activities such as anti-cancer, anti-malarial, anti-microbial and anti-asthmatic. As… read more here.
Keywords: review transition; synthesis; transition metal; metal catalyzed ... See more keywords
Recent progress in transition metal catalyzed cross coupling of nitroarenes
Sign Up to like & getrecommendations! Published in 2019 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2019.04.008
Abstract: Abstract In this review, the recent development in transition metal catalyzed cross coupling of nitroarenes was highlighted. Firstly, development of transition metal catalyzed cross coupling was simply introduced. After presenting the advantages of nitroarenes, transition… read more here.
Keywords: transition metal; catalyzed cross; cross coupling; metal catalyzed ... See more keywords
Transition metal-catalyzed conversion of aldehydes to ketones
Sign Up to like & getrecommendations! Published in 2021 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2021.08.112
Abstract: Abstract Ketones are one of the most important classes of organic compounds, and widely present in various pharmacological compounds, biologically active molecules and functional materials. Over the past few decades, transition metal-catalyzed conversion of aldehydes… read more here.
Keywords: transition metal; conversion aldehydes; metal; catalyzed conversion ... See more keywords