Metal-centered redox activity in a polymeric Cobalt(II) complex of a sterically hindered salen type ligand
Sign Up to like & getrecommendations! Published in 2020 at "Electrochimica Acta"
DOI: 10.1016/j.electacta.2020.136496
Abstract: Abstract This paper reports on the peculiarities of the metal-centered redox activity in a polymeric cobalt(II) complex of a sterically hindered tetradentate N2O2 Schiff base (salen type) ligand. A Co(III)/Co(II) redox process in the polymer… read more here.
Keywords: redox activity; redox; sterically hindered; metal centered ... See more keywords
Use of a Compact Tripodal Tris(bipyridine) Ligand to Stabilize a Single-Metal-Centered Chirality: Stereoselective Coordination of Iron(II) and Ruthenium(II) on a Semirigid Hexapeptide Macrocycle.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b00416
Abstract: Fe(II)-coordinating hexapeptides containing three 2,2'-bipyridine moieties as side chains were designed and synthesized. A cyclic hexapeptide having three [(2,2'-bipyridin)-5-yl]-d-alanine (d-Bpa5) residues, in which d-Bpa5 and Gly are alternately arranged with 3-fold rotational symmetry, coordinated with… read more here.
Keywords: hexapeptide; metal centered; centered chirality; bipyridine ... See more keywords
Enhancing Birefringence of Non-π-Conjugated Sulfate Systems Through Rare-Earth Metal-Centered Polyhedra
Sign Up to like & getrecommendations! Published in 2023 at "CrystEngComm"
DOI: 10.1039/d3ce00254c
Abstract: By the introduction of trivalent rare-earth metal-centered polyhedra [LnO6F4] (Ln = La, Gd) into alkali metal sulfates, two novel sulfate fluorides NaLn2(SO4)2F3 (Ln = La, Gd) were successfully synthesized via... read more here.
Keywords: centered polyhedra; earth metal; rare earth; metal ... See more keywords