The influence of metal centres on the exchange interaction in heterometallic complexes with oxalate-bridged cations.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt02522j
Abstract: The reaction of bis(phenanthroline)metal(ii) cations (M = Mn2+, Co2+, Ni2+, Cu2+ and Zn2+) with bis(oxalato)chromium(iii) anions in a water/ethanol solution gives rise to a series of compounds with oxalate-bridged cations, [{M(phen)2}2(μ-C2O4)][Cr(phen)(C2O4)2]2·4H2O [Mn2Cr2 (1), Co2Cr2 (2),… read more here.
Keywords: oxalate bridged; metal; mn2 co2; metal centres ... See more keywords
High-spin Metal Centres in Dipolar EPR Spectroscopy.
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DOI: 10.2533/chimia.2018.216
Abstract: The substitution of Mg2+ by Mn2+ in the bacterial DnaB helicase from Helicobacter pylori, an ATP:Mg2+-fuelled protein engine, allows electron paramagnetic resonance (EPR) spectroscopy to be performed on this system. EPR experiments make it possible… read more here.
Keywords: high spin; spin metal; epr spectroscopy; spin ... See more keywords