Visible-Light Activation of a Dissolved Organic Matter-TiO2 Complex Mediated via Ligand-to-Metal Charge Transfer.
Sign Up to like & getrecommendations! Published in 2022 at "Environmental science & technology"
DOI: 10.1021/acs.est.2c02975
Abstract: Given the widespread use of TiO2, its release into aquatic systems and complexation with dissolved organic matter (DOM) are highly possible, making it important to understand how such interactions affect photocatalytic activity under visible light.… read more here.
Keywords: organic matter; ligand metal; dissolved organic; tio2 ... See more keywords
MXene as a non-metal charge mediator in 2D layered CdS@Ti3C2@TiO2 composites with superior Z-scheme visible light-driven photocatalytic activity
Sign Up to like & getrecommendations! Published in 2019 at "Environmental Science: Nano"
DOI: 10.1039/c9en00567f
Abstract: Z-Scheme CdS@Ti3C2@TiO2 nanohybrids using MXene Ti3C2 as a non-metal charge carrier mediator exhibited superior performance in sulfachloropyridazine degradation. read more here.
Keywords: non metal; ti3c2 tio2; mxene; cds ti3c2 ... See more keywords
Visible-light-induced ligand to metal charge transfer excitation enabled phosphorylation of aryl halides.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc01858b
Abstract: We herein described a visible light induced nickel(II)-catalyzed cross-coupling of secondary phosphine oxides with aryl halides. The Ni(I) species and chlorine atom radical Cl˙ were generated via the ligand to metal charge transfer (LMCT) process… read more here.
Keywords: light induced; visible light; ligand metal; aryl halides ... See more keywords