Elucidating the Rate‐Limiting Processes in High‐Temperature Sodium‐Metal Chloride Batteries
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Science"
DOI: 10.1002/advs.202201019
Abstract: Sodium‐metal chloride batteries are considered a sustainable and safe alternative to lithium‐ion batteries for large‐scale stationary electricity storage, but exhibit disadvantages in rate capability. Several studies identify metal‐ion migration through the metal chloride conversion layer… read more here.
Keywords: chloride batteries; metal chloride; rate; metal ... See more keywords
Improving CNT-Si solar cells by metal chloride-to-oxide transformation
Sign Up to like & getrecommendations! Published in 2020 at "Nano Research"
DOI: 10.1007/s12274-020-2648-5
Abstract: Transitional metal oxides (TMOs) are important functional materials in silicon-based and thin-film optoelectronics. Here, TMOs are applied in carbon nanotube (CNT)-Si solar cells by spin-coating solutions of metal chlorides that undergo favorable transformation in ambient… read more here.
Keywords: cells metal; improving cnt; transformation; cnt solar ... See more keywords
A Temperature-Dependent Thermodynamic Model Derived from Heat Capacity of Metal Chloride Aqueous Solutions
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Chemical & Engineering Data"
DOI: 10.1021/acs.jced.7b00483
Abstract: In this work, a temperature-dependent thermodynamic model based on heat capacity was proposed to predict the osmotic and mean ion activity coefficients of metal chloride aqueous solutions. The CaCl2–H2O system was used to verify the… read more here.
Keywords: dependent thermodynamic; model; temperature dependent; thermodynamic model ... See more keywords
Concentration Flow Cells Based on Chloride-Ion Extraction and Insertion with Metal Chloride Electrodes for Efficient Salinity Gradient Energy Harvest
Sign Up to like & getrecommendations! Published in 2018 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.8b03657
Abstract: Salinity gradient (SG) is a natural and renewable energy source existing in estuaries, and can also be produced during various desalination and industrial processes. Here, a new method is proposed to efficiently recover SG energy… read more here.
Keywords: extraction insertion; energy; spectroscopy; chloride electrodes ... See more keywords
Low dimensional and frustrated antiferromagnetic interactions in transition metal chloride complexes with simple amine ligands
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DOI: 10.1039/c8ce01901k
Abstract: New transition metal chloride complexes with hydrazinium and methylhydroxylamine ligands are reported featuring low dimensional and frustrated magnetic interactions. read more here.
Keywords: metal chloride; transition metal; dimensional frustrated; low dimensional ... See more keywords
Metal chloride anion based ionic liquids: synthesis, characterization and evaluation of performance in hydrogen sulfide oxidative absorption
Sign Up to like & getrecommendations! Published in 2022 at "RSC Advances"
DOI: 10.1039/d2ra01494g
Abstract: Three metal chloride anion based ionic liquids (MCABILs) were synthesized and characterized for high conversion of hydrogen sulfide (H2S). The MCABILs were synthesized via metathesis reaction and characterized by chemical spectroscopy such as FTIR, UV-Vis… read more here.
Keywords: anion based; metal chloride; chloride anion; ionic liquids ... See more keywords
Metal chloride-catalyzed acetylation of starch: Synthesis and characterization
Sign Up to like & getrecommendations! Published in 2018 at "International Journal of Polymer Analysis and Characterization"
DOI: 10.1080/1023666x.2018.1512465
Abstract: Abstract Acylation of polysaccharides is a commercially important reaction and is usually performed in a process involving the polysaccharide, an acid anhydride, and an inorganic acid. As an alternative to inorganic acid, many catalysts, including… read more here.
Keywords: metal; acetylation starch; characterization; metal chloride ... See more keywords
In Situ Formation of Al(Fe)/Cl Metal Chloride Complexes and Evaluation of Their Catalytic Properties in the Reaction of Ethylene Oligomerization
Sign Up to like & getrecommendations! Published in 2017 at "Russian Journal of Applied Chemistry"
DOI: 10.1134/s1070427217120059
Abstract: According to FT-IR and UV spectroscopic data, the interaction of the Al/Fe alloy with tert-butyl chloride results in that AlCl4–, Al2Cl7–, and FeCl2+ ion complexes, Fe3+ ions, and AlCl3 molecular form are produced in situ… read more here.
Keywords: formation metal; situ formation; chloride complexes; chloride ... See more keywords
2,3-Dibutoxynaphthalene-based tetralactam macrocycles for recognizing precious metal chloride complexes
Sign Up to like & getrecommendations! Published in 2019 at "Beilstein Journal of Organic Chemistry"
DOI: 10.3762/bjoc.15.146
Abstract: Two new tetralactam macrocycles with 2,3-dibutoxynaphthalene groups as sidewalls have been synthesized and characterized. The macrocycle containing isophthalamide bridges can bind square-planar chloride coordination complexes of gold(III), platinum(II), and palladium(II) in CDCl3, while the macrocycle… read more here.
Keywords: precious metal; macrocycle; chloride; tetralactam macrocycles ... See more keywords