Tuning electrical conductance of molecular junctions via multipath Ru-based metal complex wire
Sign Up to like & getrecommendations! Published in 2019 at "Indian Journal of Physics"
DOI: 10.1007/s12648-019-01560-1
Abstract: AbstractWe have properly investigated the electrical conductance of ruthenium-tris-bipyridine (RuBpy) metal complex molecule by using quantum chemistry package supported by non-equilibrium Green’s function code. Our results reveal that RuBpy molecule possesses magnetic properties as well… read more here.
Keywords: metal complex; conductance; electrical conductance; conductance molecular ... See more keywords
Fluorescent probes for biothiols based on metal complex
Sign Up to like & getrecommendations! Published in 2020 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2020.213638
Abstract: Abstract Biothiols are small molecules with important physiological functions. Their detection is mainly achieved by changing the fluorescence emission of fluorophores by the nucleophilic reaction ability of sulfhydryl groups. In recent years, based on the… read more here.
Keywords: metal complex; probes biothiols; metal; metal complexes ... See more keywords
Peroxides in metal complex catalysis
Sign Up to like & getrecommendations! Published in 2021 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2021.213859
Abstract: Abstract Peroxides form an important class of chemicals in which two oxygen atoms are linked together by a single covalent bond (R−O−O−R, R=H, SO3K, alkyl, etc.), with a wide range of applications in medicine, industry,… read more here.
Keywords: metal; peroxides metal; coordination; metal complex ... See more keywords
Unusual metal complex of cadinane sesquiterpene alkaloid and new neolignan glycosides from Alangium alpinum.
Sign Up to like & getrecommendations! Published in 2018 at "Fitoterapia"
DOI: 10.1016/j.fitote.2017.12.008
Abstract: One unusual metal complex of cadinane sesquiterpene alkaloid (1), one new cadinane sesquiterpene alkaloid (2) and two new neolignan glycosides (3-4) along with six known cadinane sesquiterpene derivatives (5-10), nineteen known phenolic glycosides (11-29) were… read more here.
Keywords: metal complex; sesquiterpene alkaloid; cadinane; cadinane sesquiterpene ... See more keywords
Metal complex based delayed fluorescence materials
Sign Up to like & getrecommendations! Published in 2019 at "Organic Electronics"
DOI: 10.1016/j.orgel.2019.02.022
Abstract: Abstract This review mainly focuses on the topics related to metal complex based delayed fluorescence (DF) materials including their molecular design principle, photophysical studies, as well as their performance in the device settings. Due to… read more here.
Keywords: metal complex; fluorescence; metal; delayed fluorescence ... See more keywords
Two Chiral Metal Complex Templated Aluminoborates Constructed from Three Types of Oxoboron Clusters.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00384
Abstract: The two acentric aluminoborates (ABOs) [M(dap)3]2{Al[B5O7(OH)3][B5O8(OH)2][B6O9(OH)2]} (M and dap represent Co(1)/Ni(2) and 1,2-diaminopropane, respectively) templated by chiral metal complexes (CMCs) have been solvothermally synthesized. The isostructural 1 and 2 crystallize in the chiral space group… read more here.
Keywords: metal complex; wavelike layers; two chiral; chiral metal ... See more keywords
[2 + 2]-type Reaction of Metal-Metal σ-Bond with Fullerene Forming an η1-C60 Metal Complex: Mechanistic Details of Formation Reaction and Prediction of a New η1-C60 Metal Complex.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b00902
Abstract: C60[CpRu(CO)2]2 is only one transition-metal fullerene complex with pure η1-coordinated bonds, which was recently synthesized through the reaction between dinuclear Ru complex [CpRu(CO)2]2 and C60. Though new properties can be expected in the η1-coordinated metal-fullerene… read more here.
Keywords: metal complex; bond; fullerene; metal ... See more keywords
High-Throughput Approach for Facile Access to Hetero-Dinuclear Synergistic Metal Complex for H2O2 Activation and Its Implications.
Sign Up to like & getrecommendations! Published in 2023 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c21955
Abstract: Hetero-dinuclear synergic catalysis is a promising approach for improving catalytic performance. However, employing it is challenging because the design principles for the metal complex are still not well understood. Further, these complexes have a broader… read more here.
Keywords: metal complex; h2o2; h2o2 activation; hetero dinuclear ... See more keywords
Bio-proton coupled semiconductor/metal-complex hybrid photoelectrocatalytic interface for efficient CO2 reduction
Sign Up to like & getrecommendations! Published in 2019 at "Green Chemistry"
DOI: 10.1039/c8gc03066a
Abstract: Aimed at high-efficiency biomimetic CO2 photoelectrochemical conversion, a bio-proton coupling metal-complex/semiconductor hybrid photoelectrocatalytic interface (Ru-BNAH/TiO2/Cu2O) was constructed by covalently modifying an in situ proton-transfer functionized molecular catalyst (Ru-BNAH) on the surface of a TiO2/Cu2O composite… read more here.
Keywords: semiconductor; metal complex; proton; photoelectrocatalytic interface ... See more keywords
Attempt to visualize terminal structure on a specific facet in polymer–metal complex nanocrystals
Sign Up to like & getrecommendations! Published in 2018 at "RSC Advances"
DOI: 10.1039/c8ra02165a
Abstract: We have successfully visualized the surface terminal structure of polymer–metal complex [{Cu2(μ-Br)2(PPh3)2}(μ-bpy)]n nanocrystals (NCs) using Prussian blue (PB) nanoparticles (NPs). From TEM observation and analysis of the electron beam diffraction pattern, it was found that… read more here.
Keywords: metal complex; 010 plane; terminal structure; polymer metal ... See more keywords
Enhancement of photocatalytic H2 production by metal complex electrostatic adsorption on TiO2 (B) nanosheets
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Chemistry A"
DOI: 10.1039/c8ta10421b
Abstract: The assembly of cocatalysts on a semiconductor is a key way to promote the activity in solar hydrogen production. read more here.
Keywords: production metal; photocatalytic production; complex electrostatic; metal complex ... See more keywords