Double-metal cyanide-supported Pd catalysts for highly efficient hydrogenative ring-rearrangement of biomass-derived furanic aldehydes to cyclopentanone compounds
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2019.08.036
Abstract: Abstract The hydrogenative ring-rearrangement of biomass-derived furanic aldehydes (furfural or 5-hydroxymethyl furfural) to cyclopentanone compounds (cyclopentanone or 3-hydroxymethyl cyclopentanone) is of great significance for high-value chemicals. The Bronsted acid in metal-support bifunctional catalysts causes a… read more here.
Keywords: cyclopentanone compounds; cyclopentanone; biomass; furanic aldehydes ... See more keywords
In-situ Raman spectroscopic insight into charge delocalization-improved electrical conductivity in metal-cyanide frameworks.
Sign Up to like & getrecommendations! Published in 2022 at "Nanoscale"
DOI: 10.1039/d2nr05285g
Abstract: Porous crystalline materials (PCMs) have attracted widespread attention due to their high porosity and chemical tunability. To solve the problem of the low electrical conductivity of traditional PCMs, a guest-promoted approach has been developed to… read more here.
Keywords: cyanide frameworks; metal cyanide; conductivity; conductivity metal ... See more keywords
Enhanced removal of metal-cyanide complexes from wastewater by Fe-impregnated biochar: Adsorption performance and removal mechanism.
Sign Up to like & getrecommendations! Published in 2023 at "Chemosphere"
DOI: 10.2139/ssrn.4361187
Abstract: Metal-cyanide complexes are common contaminants in industrial wastewater. Removal of these refractory contaminants is essential before their discharge into the environment. This study investigated a biochar (BC)-based sorbent material that could be applied for the… read more here.
Keywords: adsorption; cyanide complexes; removal; metal cyanide ... See more keywords
Highly Active Heterogeneous Double Metal Cyanide Catalysts for Ring-Opening Polymerization of Cyclic Monomers
Sign Up to like & getrecommendations! Published in 2022 at "Polymers"
DOI: 10.3390/polym14122507
Abstract: A series of heterogeneous Zn-Co double metal cyanide (DMC) catalysts were investigated for ring-opening polymerization (ROP) of various cyclic monomers. Notably, inexpensive and commonly used organic solvents such as acetone, N,N-dimethylacetamide, N,N-dimethylformamide, dimethyl sulfoxide, nitromethane,… read more here.
Keywords: opening polymerization; metal cyanide; cyclic monomers; heterogeneous double ... See more keywords