Understanding and controlling the metal-directed assembly of terpyridine-functionalized coiled-coil peptides.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc03496j
Abstract: Metal-binding peptides are versatile building blocks in supramolecular chemistry. We recently reported a class of crystalline materials formed through a combination of coiled-coil peptide self-association and metal coordination. Here, we probe the serendipitously discovered metal… read more here.
Keywords: understanding controlling; metal; metal directed; controlling metal ... See more keywords
Metal-directed self-assembly of transition metal heterometallascorpionates.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt00683d
Abstract: The heterobimetallic complexes [Co(LtzE)3K(THF)2] [LtzE = [{4,5-(P(E)Ph2)2}tz]-; tz = 1,2,3-triazole; E = S(3), Se(4)] featuring high-spin cobalt centres, and [Ni(LtzE)3K(THF)2] [E = S(5), Se(6)] were synthesized through the self-assembly reaction of HLtzE [E = S(1),… read more here.
Keywords: self assembly; transition metal; metal; metal directed ... See more keywords
Construction of a series of metal-directed MOFs to explore their physical and chemical properties
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DOI: 10.1039/d0nj03424j
Abstract: Here, we report a series of metal-directed coordination polymers and explore their various properties. The polymeric networks show interesting properties such as selective CO2 gas adsorption, Fenton-type photocatalytic dye degradation and heterogeneous catalytic reduction of 4-nitrophenol. read more here.
Keywords: metal directed; directed mofs; series metal; construction series ... See more keywords
Redox- and metal-directed structural diversification in designed metalloprotein assemblies.
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DOI: 10.1039/d2cc02440c
Abstract: Herein we describe a designed protein building block whose self-assembly behaviour is dually gated by the redox state of disulphide bonds and the identity of exogenous metal ions. This protein construct is shown - through… read more here.
Keywords: redox metal; structural diversification; metal directed; directed structural ... See more keywords
Metal-directed self-assembly of constitutionally dynamic systems: control of the nuclearity of Pd(II)/Pt(II) metallacycles.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02955c
Abstract: Self-assembly with the square-planar Pd(II) or Pt(II) (en)M(ONO2)2 (en = ethylenediamine) complexes of ditopic ligands incorporating both N,N'-dialkyl-4,4'-bipyridinium and N-monoalkyl-4,4'-bipyridinium or N-monoalkyl-2,7-diazapyrenium moieties leads to constitutionally dynamic systems responsive to the concentration of the components.… read more here.
Keywords: constitutionally dynamic; self assembly; metal directed; directed self ... See more keywords