Group 10 Metal Dithiolene Bis(isonitrile) Complexes: Synthesis, Structures, Properties, and Reactivity
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DOI: 10.1021/acs.organomet.0c00375
Abstract: The reaction of [(Ph2C2S2)2M] (M = Ni2+, Pd2+, Pt2+) with 2 equiv of RN≡C (R = Me (a), Bn (b), Cy (c), tBu (d), 1-Ad (e), Ph (f)) yields [(Ph2C2S2)M(C≡NR)2] (M = Ni2+, 4a–f; M… read more here.
Keywords: bis isonitrile; group metal; complexes synthesis; metal dithiolene ... See more keywords
Metal–Dithiolene Bonding Contributions to Pyranopterin Molybdenum Enzyme Reactivity
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DOI: 10.3390/inorganics8030019
Abstract: Here we highlight past work on metal-dithiolene interactions and how the unique electronic structure of the metal-dithiolene unit contributes to both the oxidative and reductive half reactions in pyranopterin molybdenum and tungsten enzymes. The metallodithiolene… read more here.
Keywords: pyranopterin molybdenum; metal dithiolene; reactivity; molybdenum ... See more keywords