Metal-to-Metal Electron Transfer : a powerful tool for the design of switchable coordination compounds
Sign Up to like & getrecommendations! Published in 2018 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201701194
Abstract: Since the report of photomagnetic effects in Prussian blue Fe/Co networks 20 years ago by the japanese group of Hashimoto, a substantial family of molecular analogs have been obtained and characterized. These compounds offer a… read more here.
Keywords: coordination compounds; electron transfer; metal; metal metal ... See more keywords
Two-Step Thermoinduced Metal-to-Metal Electron Transfer and ON/OFF Photoswitching in a Molecular [Fe2Co2] Square Complex.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c02053
Abstract: A cyanide-bridged [Fe2Co2] molecular square complex, {[Fe(Tp)(CN)3]2[Co(L)2]2}(BF4)2·2CH3CN·6H2O [1; Tp = hydrotris(pyrazol-1-yl)borate and L = bis(1-ethyl-1H-imidazol-2-yl)ketone], has been synthesized and characterized fully by single-crystal X-ray diffraction, (photo)magnetic measurements, optical reflectivity, and other physical measurements. 1 exhibits… read more here.
Keywords: state; two step; metal; square complex ... See more keywords