Single-crystal-to-single-crystal mediated metal exchange from Zn(II) to Cu(II) and diverse structures in Zn/Cu coordination polymers using pyridylmethionine ligand
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2020.129527
Abstract: Abstract A reaction of 2-((pyridin-4-yl)methylamino)-4-(methylthio)butanoic acid (HL) and Zn(OAc)2.2H2O afforded a hexacoodinated coordination polymer of [Zn(L)(HL)(H2O)2]n (Zn-1). When the single crystals of Zn-1, are suspended in water-DMF (2:1) solution of Cu(OAc)2.H2O, a quantitative metal exchange… read more here.
Keywords: crystal single; single crystal; coordination; metal exchange ... See more keywords
Revisiting the incorporation of Ti(IV) in UiO-type metal-organic frameworks: metal exchange versus grafting and their implications on photocatalysis
Sign Up to like & getrecommendations! Published in 2017 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.7b03320
Abstract: The inclusion of Ti(IV) in water-stable metal-organic frameworks has been proposed as a strategy for the generation of high surface area heterogeneous photocatalysts, with UiO-66 being a promising candidate. We find that the site of… read more here.
Keywords: metal organic; metal; metal exchange; organic frameworks ... See more keywords
Dynamic Metal Exchange between a Metalloid Silver Cluster and Silver(I) Thiolate.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c03269
Abstract: Although a homometallic (isotopic metal) exchange reaction has been reported, the in-depth understanding of the interaction between a metalloid cluster and the homometal (representing the same metal element as the metalloid cluster) thiolate is quite… read more here.
Keywords: silver; metalloid cluster; metal exchange; metalloid ... See more keywords
Synthesis and Characterization of New Counterion-Substituted Triacylgermenolates and Investigation of Selected Metal–Metal Exchange Reactions
Sign Up to like & getrecommendations! Published in 2022 at "Organometallics"
DOI: 10.1021/acs.organomet.2c00256
Abstract: The synthetic process to obtain triacylgermenolates with alternated counterions by single-electron-transfer reactions or by a direct approach is described. The formation of these derivatives was confirmed by NMR spectroscopy and UV–vis spectroscopy. Moreover, metal–metal exchange… read more here.
Keywords: exchange reactions; spectroscopy; metal exchange; metal ... See more keywords
Harnessing Structural Dynamics in a 2D Manganese-Benzoquinoid Framework To Dramatically Accelerate Metal Transport in Diffusion-Limited Metal Exchange Reactions.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b06774
Abstract: Postsynthetic metal exchange represents a powerful synthetic method to generate metal-organic frameworks (MOFs) that are not accessible through direct synthesis, yet it is often hampered by slow reaction kinetics and incomplete exchange. While studies of… read more here.
Keywords: framework; transport; metal; exchange reactions ... See more keywords
Magnesium(II) and cadmium(II) octaphenyltetraazaporphyrinates in metal exchange reaction with MnCl2 in DMSO
Sign Up to like & getrecommendations! Published in 2017 at "Russian Journal of Inorganic Chemistry"
DOI: 10.1134/s0036023617040222
Abstract: Reaction kinetics of metal exchange of Mg(II) and Cd(II) octaphenyltetraazaporphynates with MnCl2 in DMSO has been studied by spectrophotometry. Kinetic parameters of the metal exchange reaction have been determined. Possible stoichiometric reaction mechanism has been… read more here.
Keywords: mncl2 dmso; exchange reaction; reaction; metal exchange ... See more keywords