Metal- and halogen-free one-pot synthesis of functional oligomers by tetra-n-butylammonium acetate/alcohol system
Sign Up to like & getrecommendations! Published in 2019 at "Polymer Bulletin"
DOI: 10.1007/s00289-019-02917-6
Abstract: In this study, ring-opening polymerization of glycidyl phenyl ether (GPE) is performed using tetra-n-butylammonium acetate (n-Bu4NOAc) as a metal- and halogen-free initiator. Various alcohols are used as chain transfer agents (CTAs), of which ethanol yields… read more here.
Keywords: tetra butylammonium; metal halogen; butylammonium acetate; alcohol ... See more keywords
Transition from metal-ligand bonding to halogen bonding involving a metal as halogen acceptor a study of Cu, Ag, Au, Pt, and Hg complexes
Sign Up to like & getrecommendations! Published in 2017 at "Chemical Physics Letters"
DOI: 10.1016/j.cplett.2017.05.045
Abstract: Abstract Utilizing all-electron Dirac-exact relativistic calculations with the Normalized Elimination of the Small Component (NESC) method and the local vibrational mode approach, the transition from metal-halide to metal halogen bonding is determined for Au-complexes interacting… read more here.
Keywords: metal halogen; transition metal; halogen bonding; metal ... See more keywords