Dynamic Metal–Ligand Interaction of Synergistic Polymers for Bistable See‐Through Electrochromic Devices
Sign Up to like & getrecommendations! Published in 2021 at "Advanced Materials"
DOI: 10.1002/adma.202104413
Abstract: Bistable electrochromic materials are a promising alternative solution to reduce energy consumption in displays. Limited by the mechanism and lack of a design strategy, only a few electrochromic materials have truly been able achieve bistability.… read more here.
Keywords: dynamic metal; electrochromic materials; interaction synergistic; ligand ... See more keywords
A model electronic Hamiltonian to describe low‐lying d–d and metal‐to‐ligand charge‐transfer excited states of [Fe(bpy)3]2+
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.26444
Abstract: A simple practical method to compute both d–d and metal‐to‐ligand charge‐transfer (MLCT) excited states of iron(II) polypyridyl complexes is proposed for use in simulation studies. Specifically, a model electronic Hamiltonian developed previously for d–d excited… read more here.
Keywords: ligand charge; low lying; model; metal ligand ... See more keywords
Identifying the Stoichiometry of Metal/Ligand Complex by Coupling Spectroscopy and Modelling: a Comprehensive Study on Two Fluorescent Molecules Specific to Lead
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Fluorescence"
DOI: 10.1007/s10895-019-02405-0
Abstract: Two new chemosensors for lead (II) were synthesized based on 5-((anthracen-9-ylmethylene) amino)quinolin-10-ol (ANQ). ANQ was modified in the para position of the imine group via a methoxy link either with methylmethacrylate (ANQ-MMA) or styrene (ANQ-ST).… read more here.
Keywords: fluorescent; ligand complex; study; metal ligand ... See more keywords
Synthesis of platinum single-site centers through metal-ligand self-assembly on powdered metal oxide supports
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2018.07.004
Abstract: Abstract Developing single-site metal catalysts has been regarded as a promising strategy to improve activity and selectivity in heterogeneous catalysis. Here, we report a metal-ligand self-assembly method to create Pt single-site centers on powdered oxide… read more here.
Keywords: self assembly; single site; ligand self; metal ligand ... See more keywords
Ambient-pressure highly active hydrogenation of ketones and aldehydes catalyzed by a metal-ligand bifunctional iridium catalyst under base-free conditions in water
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2021.04.023
Abstract: Abstract A green, efficient, and high active catalytic system for the hydrogenation of ketones and aldehydes to produce corresponding alcohols under atmospheric-pressure H2 gas and ambient temperature conditions was developed by a water-soluble metal-ligand bifunctional… read more here.
Keywords: water; catalyst; metal ligand; hydrogenation ketones ... See more keywords
Facile construction of terpridine-based metallo-polymers in hydrogels, crystals and solutions directed by metal ions.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of colloid and interface science"
DOI: 10.1016/j.jcis.2018.03.051
Abstract: Driven by tunable metal-ligand interactions, a polydentate ligand TC containing terpyridine and carboxylic acid units was developed to construct metallo-polymers that showed multiple aggregation modes with controlled macroscopic properties. In the presence of different kind… read more here.
Keywords: based metallo; metallo polymers; metal ligand; metallo ... See more keywords
Electronic properties and metal-ligand bonding situation in Eu(III) complexes containing tris(pyrazolyl)borate and phenantroline ligands
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Luminescence"
DOI: 10.1016/j.jlumin.2016.10.023
Abstract: Abstract In this paper we report the preparation, characterization (infrared absorption spectroscopy, photoluminescence, and thermogravimetric analysis), and DFT based electronic structure calculations (GKS-EDA), used to shed light into the metal-ligand bonding situation, of a set… read more here.
Keywords: bonding situation; containing tris; ligand bonding; metal ligand ... See more keywords
Metal–ligand bonds in [(X4R4)Fe(CO)3] (X = Si, Ge, Sn; R = SiH3, SiF3, F, Cl, Br, SiCl3, SiBr3, H, CH3, Si(CH3)3, Si(t-Bu)2Me) compounds
Sign Up to like & getrecommendations! Published in 2020 at "Polyhedron"
DOI: 10.1016/j.poly.2019.114213
Abstract: Abstract This project deals with the study of the structure and the nature of the metal–ligand bonds in [(X4R4)Fe(CO)3] (X = Si, Ge, Sn; R = SiH3, SiF3, F, Cl, Br, SiCl3, SiBr3, H, CH3, Si(CH3)3, Si(t-Bu)2Me) compounds and… read more here.
Keywords: ch3; ligand bonds; sih3 sif3; metal ligand ... See more keywords
A novel type of self-healing silicone elastomers with reversible cross-linked network based on the disulfide, hydrogen and metal-ligand bonds
Sign Up to like & getrecommendations! Published in 2020 at "Progress in Organic Coatings"
DOI: 10.1016/j.porgcoat.2020.105661
Abstract: Abstract Herein, we report an innovative cross-linked network of silicone elastomer with good stretchability, thermal stability and autonomous self-healing. This type of elastomers was easily prepared by aminopropyl terminated polydimethylsiloxane (A-PDMS), thioctic acid (TA) and… read more here.
Keywords: self healing; metal ligand; silicone elastomers; network ... See more keywords
Metal-Ligand Interactions and Their Roles in Controlling Nanoparticle Formation and Functions.
Sign Up to like & getrecommendations! Published in 2023 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.3c00156
Abstract: ConspectusFunctional nanoparticles (NPs) have been studied extensively in the past decades for their unique nanoscale properties and their promising applications in advanced nanosciences and nanotechnologies. One critical component of studying these NPs is to prepare… read more here.
Keywords: control; ligand; reduction; metal ligand ... See more keywords
Decoupling Bulk Mechanics and Mono- and Multivalent Ion Transport in Polymers Based on Metal–Ligand Coordination
Sign Up to like & getrecommendations! Published in 2018 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.8b02633
Abstract: Decoupling bulk mechanics and ion conduction in conventional ion conducting polymers is challenging due to their mutual dependence on segmental chain dynamics. Polymers based on dynamic metal–ligand coordination are promising materials toward this aim. This… read more here.
Keywords: polymers based; metal ligand; ion; mechanics ... See more keywords