Metal-Mediated DNA Nanotechnology in 3D: Structural Library by Templated Diffraction.
Sign Up to like & getrecommendations! Published in 2023 at "Advanced materials"
DOI: 10.1002/adma.202201938
Abstract: DNA double helices containing metal-mediated DNA (mmDNA) base pairs have been constructed from Ag+ and Hg2+ ions between pyrimidine:pyrimidine pairs with the promise of nanoelectronics. Rational design of mmDNA nanomaterials has been impractical without a… read more here.
Keywords: mediated dna; metal mediated; dna; nanotechnology ... See more keywords
Magnetic molecularly imprinted polymer based on dynamically established metal-mediated binding sites for the determination of trace captopril in rat plasma.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of separation science"
DOI: 10.1002/jssc.202300092
Abstract: Therapeutic drug monitoring of captopril, which is a commonly used antihypertensive agents in clinical practice, is necessary. However, matrix effect induced pretreatment is the bottleneck for determination. Metal-mediated molecularly imprinted polymers, an essential branch of… read more here.
Keywords: molecularly imprinted; captopril; metal mediated; imprinted polymer ... See more keywords
Nucleic acid duplexes with metal-mediated base pairs and their structures
Sign Up to like & getrecommendations! Published in 2019 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2019.05.007
Abstract: Abstract Metal-mediated base pairs represent a topical area of research at the border of bioinorganic chemistry, supramolecular coordination chemistry and DNA nanotechnology. In a metal-mediated base pair, the hydrogen bonds of a canonical base pair… read more here.
Keywords: metal mediated; mediated base; base; chemistry ... See more keywords
Triazole-Peptide Conjugate as a Modulator of Aβ-Aggregation, Metal-Mediated Aβ-Aggregation, and Cytotoxicity.
Sign Up to like & getrecommendations! Published in 2023 at "ACS chemical neuroscience"
DOI: 10.1021/acschemneuro.3c00041
Abstract: Amyloid-β (Aβ) aggregation plays a key role in the pathogenesis of Alzheimer's disease (AD). Along with this, the presence of redox-active metals like Cu2+ further enhances Aβ aggregation, oxidative stress, and cellular toxicity. In this… read more here.
Keywords: triazole peptide; aggregation; metal mediated; ds2 ... See more keywords
Photo- and Metal-Mediated Deconstructive Approaches to Cyclic Aliphatic Amine Diversification
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c01318
Abstract: Described herein are studies toward the core modification of cyclic aliphatic amines using either a riboflavin/photo-irradiation approach or Cu(I) and Ag(I) to mediate the process. Structural remodeling of cyclic amines is explored through oxidative C–N… read more here.
Keywords: photo; metal mediated; persulfate; photo metal ... See more keywords
Expanding Transition Metal-Mediated Bioorthogonal Decaging to Include C–C Bond Cleavage Reactions
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c01960
Abstract: The ability to control the activation of prodrugs by transition metals has been shown to have great potential for controlled drug release in cancer cells. However, the strategies developed so far promote the cleavage of… read more here.
Keywords: cleavage; metal mediated; bond cleavage; transition metal ... See more keywords
Total Synthesis of the Caged Indole Alkaloid Arboridinine Enabled by aza-Prins and Metal-Mediated Cyclizations.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b07724
Abstract: Although alkaloid natural products possess incredible diversity when considered broadly, certain domains are sometimes shared by several members, even from different sub-collections. Such homology can point to potential synthetic strategies. Herein, we highlight how such… read more here.
Keywords: metal mediated; arboridinine; aza prins; total synthesis ... See more keywords
Design of metal-mediated protein assemblies via hydroxamic acid functionalities.
Sign Up to like & getrecommendations! Published in 2021 at "Nature protocols"
DOI: 10.1038/s41596-021-00535-z
Abstract: The self-assembly of proteins into sophisticated multicomponent assemblies is a hallmark of all living systems and has spawned extensive efforts in the construction of novel synthetic protein architectures with emergent functional properties. Protein assemblies in… read more here.
Keywords: protein; construction; protein assemblies; metal ... See more keywords
Metal-mediated synthesis of pyrrolines
Sign Up to like & getrecommendations! Published in 2019 at "RSC Advances"
DOI: 10.1039/c8ra10247c
Abstract: The five-membered, nitrogen-containing pyrroline ring is a privileged structure. Pyrrolines—the dihydro derivatives of pyrroles—have three structural isomer classes: 1-, 2- and 3-pyrrolines. A review on metal-mediated synthesis of the three classes of pyrrolines is given. read more here.
Keywords: metal mediated; synthesis pyrrolines; mediated synthesis;
Network-supported, metal-mediated catalysis: progress and perspective
Sign Up to like & getrecommendations! Published in 2020 at "Reaction Chemistry and Engineering"
DOI: 10.1039/d0re00229a
Abstract: Metal-mediated chemical reactions have been a vital area of research for over a century. Recently, there has been increasing effort to improve the performance of metal-mediated catalysis by optimizing the structure and chemical environment of… read more here.
Keywords: metal; metal mediated; network supported; mediated catalysis ... See more keywords
Metal-mediated DNA base pairing of easily prepared 2-oxo-imidazole-4-carboxylate nucleotides
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc00926a
Abstract: Metal-mediated DNA base pairs, which consist of two ligand-type artificial nucleobases and a bridging metal ion, have attracted increasing attention in recent years as a different base pairing mode from natural base pairing. Metal-mediated base… read more here.
Keywords: metal mediated; dna; base pairing; metal ... See more keywords