Operando UV–Vis spectroscopy as potential in-line PAT system for size determination of functioning metal nanocatalysts
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Engineering Science"
DOI: 10.1016/j.ces.2020.115821
Abstract: Abstract Metal nanoparticle-catalyzed reactions such as hydrogenation, cross-coupling, carbonylation, and hydroformylation reactions are the most widely used reactions in the pharmaceutical and fine chemical industries. However, there is no operando spectroscopic technique that exists to… read more here.
Keywords: operando vis; vis spectroscopy; line; metal nanocatalysts ... See more keywords
Electrocatalytic nitrate/nitrite reduction to ammonia synthesis using metal nanocatalysts and bio-inspired metalloenzymes
Sign Up to like & getrecommendations! Published in 2021 at "Nano Energy"
DOI: 10.1016/j.nanoen.2021.106088
Abstract: Abstract Ammonia (NH3) is attracted as a potential carbon free energy carrier and as important feedstock for most of the fertilizers, chemicals, pharmaceutical related products. NH3 is industrially produced by conventional Haber–Bosch process under harsh… read more here.
Keywords: using metal; metal nanocatalysts; bio inspired; nitrate nitrite ... See more keywords
Orbitalwise Coordination Number for Predicting Adsorption Properties of Metal Nanocatalysts.
Sign Up to like & getrecommendations! Published in 2017 at "Physical review letters"
DOI: 10.1103/physrevlett.118.036101
Abstract: We present the orbitalwise coordination number CN^{α} (α=s or d) as a reactivity descriptor for metal nanocatalysts. With the noble metal Au (5d^{10}6s^{1}) as a specific case, the CN^{s} computed using the two-center s-electron hopping… read more here.
Keywords: adsorption; adsorption properties; predicting adsorption; orbitalwise coordination ... See more keywords
Pt-Free Metal Nanocatalysts for the Oxygen Reduction Reaction Combining Experiment and Theory: An Overview
Sign Up to like & getrecommendations! Published in 2021 at "Molecules"
DOI: 10.3390/molecules26216689
Abstract: The design and manufacture of highly efficient nanocatalysts for the oxygen reduction reaction (ORR) is key to achieve the massive use of proton exchange membrane fuel cells. Up to date, Pt nanocatalysts are widely used… read more here.
Keywords: free metal; nanocatalysts oxygen; metal nanocatalysts; reduction reaction ... See more keywords