Hydrogen‐Bonded Polyimide/Metal‐Organic Framework Hybrid Membranes for Ultrafast Separations of Multiple Gas Pairs
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DOI: 10.1002/adfm.201903243
Abstract: Membranes have seen a growing role in mitigating the extensive energy used for gas separations. Further expanding their effectiveness in reducing the energy penalty requires a fast separation process via a facile technique readily integrated… read more here.
Keywords: polyimide metal; membrane; hydrogen; metal organic ... See more keywords
Metal–Organic Framework‐Derived Graphitic Nanoribbons Anchored on Graphene for Electroionic Artificial Muscles
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DOI: 10.1002/adfm.201910326
Abstract: To achieve large bending displacement and fast response time under ultralow input voltages, as well as improved durability, advanced high‐performance ionic actuators still face crucial design challenges that must be resolved. Here, hierarchically porous and… read more here.
Keywords: artificial muscles; nanoribbons anchored; anchored graphene; electroionic artificial ... See more keywords
The Art of Integrated Functionalization: Super Stable Black Phosphorus Achieved through Metal‐Organic Framework Coating
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DOI: 10.1002/adfm.202002232
Abstract: Black phosphorus (BP) is a promising 2D nanomaterial with a great potential in various areas, while its intrinsic instability greatly suppresses practical applications, particularly under harsh conditions (e.g., high temperature). Herein, BP functionalization with Al… read more here.
Keywords: integrated functionalization; functionalization; metal organic; black phosphorus ... See more keywords
Molecular‐Scale Interface Engineering of Metal–Organic Frameworks toward Ion Transport Enables High‐Performance Solid Lithium Metal Battery
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DOI: 10.1002/adfm.202003945
Abstract: Metal–organic frameworks (MOFs) have drawn considerable interest as solid electrolytes (SEs) by virtue of their talents for rational design as ion channels. The crystal interface plays a significant role in ion transport and is thus… read more here.
Keywords: interface; ion transport; metal organic; ion ... See more keywords
Aluminum Metal–Organic Batteries with Integrated 3D Thin Film Anodes
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DOI: 10.1002/adfm.202004573
Abstract: Aluminum 3D thin film anodes fully integrated with a separator are fabricated by sputtering and enable rechargeable aluminum metal batteries with high power performance. The 3D thin film anodes have an approximately four to eight… read more here.
Keywords: aluminum metal; metal organic; thin film; film anodes ... See more keywords
A 3D Cu‐Naphthalene‐Phosphonate Metal–Organic Framework with Ultra‐High Electrical Conductivity
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DOI: 10.1002/adfm.202007294
Abstract: A conductive phosphonate metal–organic framework (MOF), [{Cu(H2O)}(2,6‐NDPA)0.5] (NDPA = naphthalenediphosphonic acid), which contains a 2D inorganic building unit (IBU) comprised of a continuous edge‐sharing sheet of copper phosphonate polyhedra is reported. The 2D IBUs are… read more here.
Keywords: conductivity; organic framework; metal organic; phosphonate metal ... See more keywords
Bioinspired Metal‐Organic Frameworks in Mixed Matrix Membranes for Efficient Static/Dynamic Removal of Mercury from Water
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DOI: 10.1002/adfm.202008499
Abstract: The mercury removal efficiency of a novel metal‐organic framework (MOF) derived from the amino acid S‐methyl‐L‐cysteine is presented and the process is characterized by single‐crystal X‐ray crystallography. A feasibility study is further presented on the… read more here.
Keywords: static dynamic; mixed matrix; mercury; water ... See more keywords
Diverse Metal–Organic Framework Architectures for Electromagnetic Absorbers and Shielding
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DOI: 10.1002/adfm.202100470
Abstract: Metal–organic frameworks (MOFs) and their derivatives, featuring unique 3D microstructures and enhanced electromagnetic properties, are illuminating infinite possibilities for electromagnetic functional materials and devices, receiving significant attention from domestic and foreign researchers. Herein, the design… read more here.
Keywords: architectures electromagnetic; framework architectures; diverse metal; metal organic ... See more keywords
Mixed‐Valence Ce/Zr Metal‐Organic Frameworks: Controlling the Oxidation State of Cerium in One‐Pot Synthesis Approach
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DOI: 10.1002/adfm.202102582
Abstract: Authors acknowledge financial support by MINECO (Spain) through projects, MAT2017-86992-R and MAT2016-80285-P. EVRF acknowledges MINECO for his Ramon y Cajal fellow RYC-2012-11427. The authors also would like to thank Diamond Light Source (I20-Scanning beamline) for… read more here.
Keywords: metal organic; controlling oxidation; valence metal; mixed valence ... See more keywords
Manifestation of Strongly Correlated Electrons in a 2D Kagome Metal–Organic Framework
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DOI: 10.1002/adfm.202106474
Abstract: The kagome lattice, whose electronic valence band (VB) structure includes two Dirac bands and one flat band1–3, offers a rich space to realise tuneable topological and strongly correlated electronic phases1,4 in two-dimensional (2D) and layered… read more here.
Keywords: metal organic; metal; strongly correlated; manifestation strongly ... See more keywords
Metal‐Organic Frameworks Derived Titanium Oxides via Soft Interface Adaptive Transformation
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DOI: 10.1002/adfm.202107260
Abstract: High‐temperature treatment of metal‐organic frameworks (MOFs) is a promising route to prepare a variety of functional materials with diverse applications. However, it is challenging to prepare highly crystalline metal oxides such as TiO2 with controllable… read more here.
Keywords: interface; adaptive transformation; soft interface; metal organic ... See more keywords