Fabrication of High-Valence MOF Membrane with Metal-Oxo Cluster Source: Opportunities and Challenges.
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DOI: 10.1002/cplu.202200462
Abstract: Metal-organic framework (MOF) represents a new class of organic-inorganic hybrid microporous crystalline material. Owing to their high surface areas, tunable pore aperture, and rich functional groups, MOF materials have shown great promise in gas storage,… read more here.
Keywords: oxo cluster; metal oxo; valence mof; high valence ... See more keywords
Visible light generation of high-valent metal-oxo intermediates and mechanistic insights into catalytic oxidations.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2020.111246
Abstract: High-valent metal-oxo complexes play central roles as active oxygen atom transfer (OAT) agents in many enzymatic and synthetic oxidation catalysis. This review focuses on our recent advances in application of photochemical approaches to probe the… read more here.
Keywords: oxo species; oxo; valent metal; high valent ... See more keywords
Bismuth for Controlled Assembly/Disassembly of Transition-Metal Oxo Clusters, Defining Reaction Pathways in Inorganic Synthesis and Nature.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b03646
Abstract: Trivalent bismuth is a unique heavy p-block ion. It is highly insoluble in water, due to strong hydrolysis tendencies, and known for low toxicity. Its lone pair is structure-directing, providing framework materials with structural flexibility,… read more here.
Keywords: oxo clusters; reaction pathways; metal; metal oxo ... See more keywords
Isolation of a Terminal Co(III)-Oxo Complex.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b07399
Abstract: Late transition metal oxo complexes with high d-electron counts have been implicated as intermediates in a wide variety of important catalytic reactions; however, their reactive nature has often significantly limited their study. While some examples… read more here.
Keywords: oxo complexes; isolation terminal; oxo; metal oxo ... See more keywords
Fatty acid capped, metal oxo clusters as the smallest conceivable nanocrystal prototypes
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc05037d
Abstract: Metal oxo clusters of the type M6O4(OH)4(OOCR)12 (M = Zr or Hf) are valuable building blocks for materials science. Here, we synthesize a series of zirconium and hafnium oxo clusters with ligands that are typically… read more here.
Keywords: metal oxo; acid; oxo clusters; fatty acid ... See more keywords
Rational synthesis of elusive organic–inorganic hybrid metal-oxo clusters: formation and post-functionalization of hexavanadates
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Science"
DOI: 10.1039/d3sc00038a
Abstract: Paving the way towards new functional materials relies increasingly on the challenging task of forming organic–inorganic hybrid compounds. In that regard, discrete atomically-precise metal-oxo nanoclusters have received increasing attention due to the wide range of… read more here.
Keywords: metal oxo; functionalization; post functionalization;