Metal-Stabilized Boronate Ester Cages.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c01719
Abstract: Molecular cages with arylboronate ester caps at the vertices are described. The cages were obtained by metal-templated polycondensation reactions of a tris(2-formylpyridine oxime) ligand with arylboronic acids. Suited templates are triflate or triflimide salts of… read more here.
Keywords: ester cages; metal stabilized; ester; boronate ester ... See more keywords
Transition-Metal-Stabilized Heavy Tetraphospholide Anions
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c08754
Abstract: Phosphorus analogues of the ubiquitous cyclopentadienyl (Cp) are a rich and diverse family of compounds, which have found widespread use as ligands in organometallic complexes. By contrast, phospholes incorporating heavier group 14 elements (Si, Ge,… read more here.
Keywords: heavy tetraphospholide; tetraphospholide anions; transition metal; metal stabilized ... See more keywords