Octahedral-based redox molecular sieve M-PKU-1: Isomorphous metal-substitution, catalytic oxidation of sec-alcohol and related catalytic mechanism
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2017.05.007
Abstract: Abstract Octahedral-based redox molecular sieves M-PKU-1 (M Cr, Fe) were synthesized by isomorphous metal-substitution and used as catalysts for catalytic dehydrogenation of sec-alcohols using H2O2 as oxidant. Various characterizations, such as X-ray diffraction Rietveld refinement… read more here.
Keywords: based redox; octahedral based; isomorphous metal; metal substitution ... See more keywords
Noble-Metal Substitution in Hemoproteins: An Emerging Strategy for Abiological Catalysis.
Sign Up to like & getrecommendations! Published in 2019 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.8b00586
Abstract: Enzymes have evolved to catalyze a range of biochemical transformations with high efficiencies and unparalleled selectivities, including stereoselectivities, regioselectivities, chemoselectivities, and substrate selectivities, while typically operating under mild aqueous conditions. These properties have motivated extensive… read more here.
Keywords: strategy; reactivity; native enzymes; metal substitution ... See more keywords
Computing the Effect of Metal Substitution in Metal–Organic Frameworks on the Recombination Times of Charge Carriers
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.0c02414
Abstract: Metal–organic frameworks (MOFs) have been attracting increasing attention in the fields of photoactive applications, for which understanding the factors governing their excited-state properties is ... read more here.
Keywords: metal organic; metal; metal substitution; effect metal ... See more keywords
Periodic Trends from Metal Substitution in Bimetallic Mo-Based Phosphides for Hydrodeoxygenation and Hydrogenation Reactions
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.7b09363
Abstract: Bimetallic phosphides are promising materials for biomass valorization, yet many metal combinations are understudied as catalysts and require further analysis to realize their superior properties. Herein, we provide the synthesis, characterization, and catalytic performance of… read more here.
Keywords: trends metal; substitution bimetallic; periodic trends; metal substitution ... See more keywords
Metal Substitution and Solvomorphism in Alkylthiolate-Bridged Zn3 and HgZn2 Metal Clusters
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DOI: 10.1021/acsomega.7b01087
Abstract: The impact of substituting Hg(II) for Zn(II) in a thiolate-bridged trinuclear cluster with parallels to a metallothionein metal cluster was investigated. A new solvomorph of [Zn(ZnL)2](ClO4)2 (1) (L = N-(2-pyridylmethyl)-N-(2-(ethylthiolato)-amine) and five solvomorphs of a… read more here.
Keywords: alkylthiolate bridged; metal; substitution solvomorphism; metal substitution ... See more keywords