Synthesis, characterization and reactivity of non-heme 1st row transition metal-superoxo intermediates
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DOI: 10.1016/j.ccr.2018.12.006
Abstract: Abstract Metalloenzymes activate dioxygen to generate metal-oxygen adducts that perform a wide range of biological functions. Among the metal-dioxygen intermediates, highly reactive metal-superoxo species are implicated as key intermediates in the catalytic cycle of various… read more here.
Keywords: synthesis characterization; metal; reactivity; metal superoxo ... See more keywords
Structure and reactivity of the first-row d-block metal-superoxo complexes.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt01402k
Abstract: In the first-row of d-block metals, ten elements are included, such as scandium (Sc, 3d1), titanium (Ti, 3d2), vanadium (V, 3d3), chromium (Cr, 3d54s1), manganese (Mn, 3d5), iron (Fe, 3d6), cobalt (Co, 3d7), nickel (Ni,… read more here.
Keywords: superoxo; superoxo complexes; iii superoxo; first row ... See more keywords