Self‐Accommodation Induced Electronic Metal–Support Interaction on Ruthenium Site for Alkaline Hydrogen Evolution Reaction
Sign Up to like & getrecommendations! Published in 2023 at "Advanced Materials"
DOI: 10.1002/adma.202301369
Abstract: Tuning the metal‐support interaction of supported metal catalysts has been found to be the most effective approach to modulating electronic structure and improving catalytic performance. But practical understanding of the charge transfer mechanism at the… read more here.
Keywords: alkaline hydrogen; metal support; support interaction; electronic metal ... See more keywords
The Synergistic Effect of Pyrrolic‐N and Pyridinic‐N with Pt Under Strong Metal‐Support Interaction to Achieve High‐Performance Alkaline Hydrogen Evolution
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Energy Materials"
DOI: 10.1002/aenm.202200110
Abstract: Developing high‐performance Pt‐based catalysts with strong metal‐support interaction (SMSI) is significant for hydrogen production by water electrolysis working at high current density conditions, but still challenging. Herein, Pt/X‐NCNT (X = 4, 8, 12, 16) with… read more here.
Keywords: metal support; strong metal; synergistic effect; support interaction ... See more keywords
Electronic Metal-Support Interaction Directing the Design of Fe(III)-Based Catalysts for Efficient Advanced Oxidation Processes by Dual Reaction Paths.
Sign Up to like & getrecommendations! Published in 2022 at "Small"
DOI: 10.1002/smll.202203269
Abstract: Persistent organic pollutants (POPs) have a huge impact on human health due to their high toxicity and non-degradability. It is still of great difficulty to develop highly efficient catalysts toward the degradation of POPs. Herein,… read more here.
Keywords: metal support; support interaction; iii; electronic metal ... See more keywords
Electronic Metal–Support Interaction Modulation of Single‐Atom Electrocatalysts for Rechargeable Zinc–Air Batteries
Sign Up to like & getrecommendations! Published in 2022 at "Small Methods"
DOI: 10.1002/smtd.202100947
Abstract: High‐performance oxygen electrocatalysts play a key role in the widespread application of rechargeable Zn–air batteries (ZABs). Single‐atom catalysts (SACs) with maximum atom efficiency and well‐defined active sites have been recognized as promising alternatives of the… read more here.
Keywords: air batteries; metal support; single atom; support interaction ... See more keywords
Kinetic Modeling of the Metal/Support Interaction for CH4 Reaction over Oxidized Pd/Al2O3
Sign Up to like & getrecommendations! Published in 2018 at "Topics in Catalysis"
DOI: 10.1007/s11244-018-1125-9
Abstract: This paper deals with the kinetics of CH4 dissociation on model Pd/Al2O3 catalysts. The adsorption and conversion of CH4 over oxidized catalysts, fresh or aged, were studied with a temporal analysis of products (TAP) reactor.… read more here.
Keywords: kinetic modeling; metal support; ch4; interaction ... See more keywords
Strong metal-support interaction effect of Pt/Nb2O5 catalysts on aqueous phase hydrodeoxygenation of 1,6-hexanediol
Sign Up to like & getrecommendations! Published in 2018 at "Catalysis Today"
DOI: 10.1016/j.cattod.2017.03.026
Abstract: Abstract A series of Pt/Nb 2 O 5 catalysts were synthesized at different temperature conditions to investigate metal-support interaction effect on the catalytic activities in the aqueous phase hydrodeoxygenation of 1,6-hexanediol at 523 K and 5.5 MPa.… read more here.
Keywords: phase hydrodeoxygenation; aqueous phase; metal support; support ... See more keywords
Elucidation of metal and support effects during ethanol steam reforming over Ni and Rh based catalysts supported on (CeO2)-ZrO2-La2O3
Sign Up to like & getrecommendations! Published in 2020 at "Catalysis Today"
DOI: 10.1016/j.cattod.2020.03.020
Abstract: Abstract Hydrogen production via steam reforming of biomass derived oxygenates is a promising environmental alternative to the use of fossil fuels. The ethanol steam reforming reaction is investigated over Ni and Rh based catalysts supported… read more here.
Keywords: metal support; ceo2 zro2; zro2; steam reforming ... See more keywords
Sintering-resistant Au/iron oxide-hydroxyapatite nanocatalysts achieved by tuning strong metal-support interactions
Sign Up to like & getrecommendations! Published in 2021 at "Catalysis Today"
DOI: 10.1016/j.cattod.2021.01.012
Abstract: Abstract Supported gold nanocatalysts have been treated as extraordinarily effective catalysts in heterogeneous catalysis field. However, their poor thermodynamic stability in reactions at elevated temperature remains to be resolved for practical applications. The strong metal-support… read more here.
Keywords: sintering resistant; metal support; support; strong metal ... See more keywords
Fine-tuning inverse metal-support interaction boosts electrochemical transformation of methanol into formaldehyde based on density functional theory
Sign Up to like & getrecommendations! Published in 2021 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2020.12.057
Abstract: Abstract Different from traditional metal-support heterogenous catalysts, inverse heterogeneous catalysts, in which the surface of metal is decorated by metal oxide, have recently attracted increasing interests owing to the unique interfacial effect and electronic structure.… read more here.
Keywords: electrochemical transformation; metal; based density; density functional ... See more keywords
Engineering stable Pt nanoparticles and oxygen vacancies on defective TiO2 via introducing strong electronic metal-support interaction for efficient CO2 photoreduction
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2019.123450
Abstract: Abstract This work for the first time reports the promoting effect of strong electronic metal-support interaction (EMSI) in Pt/TiO2-VO (VO: oxygen vacancy) for gas-phase CO2 photoreduction. A novel in-situ surface hydrogenation was developed to prepare… read more here.
Keywords: tio2; strong electronic; metal support; oxygen vacancies ... See more keywords
Metal-support interactions regulated via carbon coating – A case study of Co/SiO2 for Fischer-Tropsch synthesis
Sign Up to like & getrecommendations! Published in 2018 at "Fuel"
DOI: 10.1016/j.fuel.2018.03.195
Abstract: Abstract We demonstrate the regulation of metal-support interactions (MSI) by impregnating Co(NO3)2 as a precursor of cobalt over the silica coated with different amounts of amorphous carbon via carbonizing the glucose as a precursor in… read more here.
Keywords: carbon; metal support; tropsch synthesis; fischer tropsch ... See more keywords