Trans-Metal-Trapping Meets Frustrated-Lewis-Pair Chemistry: Ga(CH2SiMe3)3-Induced C–H Functionalizations
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.7b00549
Abstract: Merging two topical themes in main-group chemistry, namely, cooperative bimetallics and frustrated-Lewis-pair (FLP) activity, this Forum Article focuses on the cooperativity-induced outcomes observed when the tris(alkyl)gallium compound GaR3 (R = CH2SiMe3) is paired with the… read more here.
Keywords: lewis pair; trans metal; chemistry; metal trapping ... See more keywords
In Situ ‘Trans-Metal Trapping’: An Efficient Way to Extend the Scope of Aromatic Deprotometalation
Sign Up to like & getrecommendations! Published in 2018 at "Synthesis"
DOI: 10.1055/s-0036-1591953
Abstract: Deprotometalation is an efficient method to functionalize regioselectively aromatic compounds including heterocycles. This short review shows how it is possible to intercept aryllithiums (and other polar arylmetals) as soon as they are formed by in… read more here.
Keywords: trans metal; situ traps; situ; metal trapping ... See more keywords