Switch of Thermal Expansions Triggered by Itinerant Electrons in Isostructural Metal Trifluorides.
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DOI: 10.1021/acs.inorgchem.2c03499
Abstract: Manageable thermal expansion (MTE) of metal trifluorides can be achieved by introducing local structure distortion (LSD) in the negative thermal expansion ScF3. However, an open issue is why isostructural TiF3, free of LSD, exhibits positive… read more here.
Keywords: itinerant electrons; metal trifluorides; thermal expansion; switch thermal ... See more keywords