Metathetical Exchange between Metal-Metal Triple Bonds.
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DOI: 10.1021/jacs.9b13604
Abstract: The reaction of the molybdenum-molybdenum triple-bonded dimer (CO)2CpMo≡MoCp(CO)2 (Cp = η5-C5H5) with the triple-bonded dimetallynes AriPr4MMAriPr4 or AriPr6MMAriPr6 (AriPr4 = C6H3-2,6-(C6H3-2,6-Pri2)2, AriPr6 = C6H3-2,6-(C6H2-2,4,6-Pri3)2; M = Ge, Sn, or Pb) under mild condi-tions (≤80°C, 1… read more here.
Keywords: mocp; triple bonds; metal triple; metal ... See more keywords