Experimental and computational tuning of metalla-N-heterocyclic carbenes at palladium(II) and platinum(II) centers.
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DOI: 10.1039/d2dt00252c
Abstract: Palladium(II) and platinum(II) complexes featuring metalla-N-heterocyclic carbenes (7-12) were synthesised via metal-mediated coupling between equimolar cis-[MCl2(CNR)2] (R = 2,6-Me2C6H3 (Xyl), 2,4,6-Me3C6H3 (Mes)) and 2-aminopyridine or 2-aminopyrazine. Thiocyanate complexes 13-18 with two thiocyanate ligands were obtained… read more here.
Keywords: metalla heterocyclic; palladium platinum; heterocyclic carbenes;