Chemistry of group 5 metallaboranes with heterocyclic thiol ligands: a combined experimental and theoretical study.
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DOI: 10.1039/d0dt04362a
Abstract: Thermolysis of [(Cp*Nb)2(B2H6)2], 1b (Cp* = η5-C5Me5), with 2-mercaptobenzothiazole, C6H4NSCSH (MBT), and 2-mercaptobenzoxazole, C6H4NOCSH (MBO), yielded hydrogen substituted compounds 2 and 3 with a general formula [(Cp*Nb)2(B2H6)(B2H5L)] (2: L = C6H4NSCS and 3: L =… read more here.
Keywords: metallaboranes heterocyclic; c6h4nscs; chemistry; group metallaboranes ... See more keywords