Spontaneous ligand nitrosation and self-assembly into a pentacopper metallacrown complex.
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DOI: 10.1039/c6dt04696g
Abstract: Upon mixing acetylacetonedioxime and copper(ii) nitrate in water, the acetylacetonedioxime is spontaneously nitrosated at the central α-carbon and four of the nitrosated ligand molecules and five Cu ions self-assemble into a pentanuclear metallacrown complex, whose… read more here.
Keywords: metallacrown; metallacrown complex; ligand nitrosation; nitrosation self ... See more keywords