A bell-like 15-metallacrown-5 complex from flexible H2Glyha ligand: Synthesis, structure and filed-induced slow magnetic relaxation
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2020.128822
Abstract: Abstract The reaction of Glycinehydroxamic acid (H2glyha) ligand, Cu(OAc)2·H2O and Dy(NO3)3·6H2O afforded an intriguing bell-like 15-Metallacrown-5 complex [Dy(OAc)Cu5(glyha)5(H2O)4]·2NO3·4H2O, which exhibit a cyclic [CuGly]5 frame and a Dy(III) ion is located at the center of the… read more here.
Keywords: metallacrown complex; slow magnetic; h2glyha ligand; like metallacrown ... See more keywords
Spontaneous ligand nitrosation and self-assembly into a pentacopper metallacrown complex.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c6dt04696g
Abstract: Upon mixing acetylacetonedioxime and copper(ii) nitrate in water, the acetylacetonedioxime is spontaneously nitrosated at the central α-carbon and four of the nitrosated ligand molecules and five Cu ions self-assemble into a pentanuclear metallacrown complex, whose… read more here.
Keywords: metallacrown; metallacrown complex; ligand nitrosation; nitrosation self ... See more keywords