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   Articles with "metallacycle" as a keyword



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Temperature- and Mechanical-Force-Responsive Self-Assembled Rhomboidal Metallacycle

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recommendations! Published in 2019 at "Organometallics"

DOI: 10.1021/acs.organomet.9b00544

Abstract: The dianthracene-based rhomboidal organoplatinum(II) metallacycle 1 was successfully obtained via coordination-driven self-assembly involving the combination of diplatinum(II) acceptor 2 and dipyri... read more here.

Keywords: force responsive; metallacycle; self assembled; mechanical force ... See more keywords

Pillar[5]arene-Containing Metallacycles and Host-Guest Interaction Caused Aggregation-Induced Emission Enhancement Platforms.

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recommendations! Published in 2020 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.0c08697

Abstract: Coordination-driven Pt metallacycles have shown potential in controllable modular self-assembly, which has made a vital contribution to biomedicine, catalysis, and multiresponsive materials. Herein, pillar[5]arene units were integrated into one skeleton through coordination-driven self-assembly, resulting in… read more here.

Keywords: emission enhancement; arene containing; metallacycle; host guest ... See more keywords
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Rationally designed Ru(ii)-metallacycle chemo-phototheranostic that emits beyond 1000 nm

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recommendations! Published in 2022 at "Chemical Science"

DOI: 10.1039/d2sc01518h

Abstract: Ruthenium complexes are emerging as potential complements to platinum drugs. They also show promise as photo-diagnostic and therapeutic agents. However, most ruthenium species studied to date as potential drugs are characterized by short excitation/emission wavelengths.… read more here.

Keywords: rationally designed; cell; designed metallacycle; metallacycle chemo ... See more keywords
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Hydrogen Bonding Directed Self-Assembly of a Binuclear Ag(I) Metallacycle into a 1D Supramolecular Polymer

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recommendations! Published in 2021 at "Molecules"

DOI: 10.3390/molecules26185719

Abstract: An Ag(I) metallacycle obtained unexpectedly during the preparation of Pd(II) complexes of the bifunctional ligand 5-([2,2′-bipyridin]-5-yl)pyrimidine-2-amine (L) has been characterized using X-ray structure determination as a binuclear, metallacyclic species [Ag2L2](SbF6)2, where both the bipyridine and… read more here.

Keywords: self assembly; metallacycle; bonding directed; hydrogen bonding ... See more keywords
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Cyclometallated Palladium(II) Complexes: An Approach to the First Dinuclear Bis(iminophosphorane)phosphane-[C,N,S] Metallacycle

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recommendations! Published in 2022 at "Molecules"

DOI: 10.3390/molecules27207043

Abstract: Treatment of bis(iminophosphorane)phosphane ligands 2a–2e with Li2PdCl4 gave a set of novel diphosphane-derived complexes bearing two metallacycle rings, each one enclosing a P=N double bond: the unprecedented bis(iminophosphorane)phosphane-[C,N,S] palladacycles. In the case of the ligand… read more here.

Keywords: iminophosphorane phosphane; metallacycle; bis iminophosphorane; bis ... See more keywords