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Metallaheteroboranes containing group 16 elements: An experimental and theoretical study

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Published in 2019 at "Journal of Organometallic Chemistry"

DOI: 10.1016/j.jorganchem.2019.01.007

Abstract: Abstract Thermolysis of diphenyl dichalcogenides, Ph2E2 (E = S, Se and Te) with an insitu generated intermediate, obtained from the reaction of [Cp*WCl4] (Cp* = η5-C5Me5) with [LiBH4·THF], yielded new tungstaheteroboranes, [(Cp*W)2(μ-EPh)(μ3-E)(μ-H)(B3H2EPh)], 1 and 2 (1: E = S; 2: E = Se),… read more here.

Keywords: theoretical study; experimental theoretical; group elements; containing group ... See more keywords