Syntheses of Square Planar Gallium Complexes and a Proton NMR Correlation Probing Metalloaromaticity.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c01908
Abstract: Syntheses of square planar (SP) coordination complexes of gallium(III) are reported herein. Using the pyridine diimine ligand (PDI), we prepared both (PDI2-)GaH (4) and (PDI2-)GaCl (5), which were spectroscopically and structurally characterized. Reduction of PDI… read more here.
Keywords: proton nmr; square planar; planar gallium; metalloaromaticity ... See more keywords
Chameleon-like Nature of Anagostic Interactions and Its Impact on Metalloaromaticity in Square-Planar Nickel Complexes
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00062
Abstract: Anagostic C–H···M (M = a metal center) intramolecular interactions, one of the most fundamental and elusive forces in organometallic chemistry, are intuitively considered as repulsive and purely electrostatic in nature because of significant metal–hydrogen distances… read more here.
Keywords: metal hydrogen; nature; square planar; metalloaromaticity ... See more keywords