Fe-Mediated Nitrogen Fixation with a Metallocene Mediator: Exploring p Ka Effects and Demonstrating Electrocatalysis.
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DOI: 10.1021/jacs.8b02335
Abstract: Substrate selectivity in reductive multielectron/proton catalysis with small molecules such as N2, CO2, and O2 is a major challenge for catalyst design, especially where the competing hydrogen evolution reaction (HER) is thermodynamically and kinetically competent.… read more here.
Keywords: nitrogen fixation; fixation metallocene; metallocene mediator; mediated nitrogen ... See more keywords