[(thf)5Ln(Ge9{Si(SiMe3)3}2)] (Ln = Eu, Sm, Yb): Capping Metalloid Germanium Cluster with Lanthanides.
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DOI: 10.1021/acs.inorgchem.3c00165
Abstract: We report the synthesis of three neutral complexes with different coordination modes of a di-silylated metalloid germanium cluster to divalent lanthanides [(thf)5Ln(ηn-Ge9(Hyp)2)] (Ln = Yb (1, n = 1); Eu (2, n = 2, 3),… read more here.
Keywords: metalloid germanium; 5ln ge9; ge9; germanium cluster ... See more keywords
Metalloid germanium cluster shears for lanthanide diiodides.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt00578j
Abstract: We report the synthesis and characterization of ionic compounds [(thf)4YbI]2[Ge9(Hyp)3]2 (1) and [(thf)5LnI]4[Ge9(Hyp)3]4 (Ln = Eu (2), Sm (3)), (Hyp = Si(SiMe3)3). All compounds were examined by UV-Vis spectroscopy and a blue luminescence of Eu2+… read more here.
Keywords: metalloid germanium; hyp; lanthanide diiodides; shears lanthanide ... See more keywords